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Rhodium-benzimidazolidin-2-ylidene catalyzed addition of arylboronic acids to aldehydes

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Abstract

Six rhodium–carbene complexes (2a–f) have been prepared and the new compounds characterized by C, H, N analyses, 1H-n.m.r. and 13C-n.m.r. Phenylboronic acid reacts with aldehydes in the presence of a catalytic amount of rhodium(I)–carbene complex, RhCl(COD)(1,3-dialkylbenzimidazolidin-2-ylidene), (2a–f), to give the corresponding aryl secondary alcohols in good yields.

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Authors and Affiliations

  1. Faculty of Science and Arts, Chemistry Department, Inönü University, 44280, Malatya, Turkey

    Ismail Özdemir, Nevin Gürbüz & Yetkin Gök

  2. Department of Chemistry, Ege University, 35100, Bornova-İzmir, Turkey

    Bekir Çetinkaya & Engin Çetinkaya

Authors
  1. Ismail Özdemir
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  2. Nevin Gürbüz
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  3. Yetkin Gök
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  4. Bekir Çetinkaya
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  5. Engin Çetinkaya
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Özdemir, I., Gürbüz, N., Gök, Y. et al. Rhodium-benzimidazolidin-2-ylidene catalyzed addition of arylboronic acids to aldehydes. Transition Met Chem 30, 367–371 (2005). https://doi.org/10.1007/s11243-004-6964-5

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  • DOI: https://doi.org/10.1007/s11243-004-6964-5

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