Skip to main content
SpringerLink
Log in

Synthesis and characterization of η3-allyl palladium(II) complexes with Ph2P(S)CHP(S)Ph2 and OC(CF3)CHCO(C4H3S) co-ligands

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

The new complexes [(η3-Me2CCMeCH2)Pd{η2-Ph2P(S)CHP(S)Ph2] (1), [(η3-Me2CCMeCH2)Pd{η2-OC(CF3) CHCO(C4H3S)}] (2) and [(η3-CH2CMeCH2)Pd{η2-OC(CF3)CHCO(C4H3S)}] (3) have been synthesized by reacting [(η3-allyl)Pd(μ-Cl)]2 with Ph2P(S)CH2P(S)Ph2 and OC(CF3)CH2CO(C4H3S) in the presence of base. All have been characterized by elemental analysis, FT-IR, 1H-n.m.r and FAB-mass spectroscopy. Spectroscopic studies suggest that both ligands are bidentate, forming six-membered Pd-S-P-C-P-S and Pd-O-C-C-C-O palladacycles, the η3-allyl group completing the coordination sphere.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  • P.M. Maitlis (1971) The Organic Chemistry of Palladium, Vol. 1 Academic Press NY, London

    Google Scholar 

  • E. Ban A.W.L. Chan J. Powell (1972) J. Organomet. Chem. 34 405

    Google Scholar 

  • S.D. Robinson B.L. Shaw (1965) J. Organomet. Chem. 3 367 Occurrence Handle10.1016/S0022-328X(00)80189-8

    Article  Google Scholar 

  • J. Powell A.W.L. Chan (1972) J. Organomet. Chem. 35 203

    Google Scholar 

  • M.R. Churchill, Chem. Commun., 625 (1965); M.R. Churchill, Inorg. Chem., 5 1608 (1966).

  • A. Musco R. Rampone P. Ganis C. Pedone (1972) J. Organomet. Chem. 34 C48

    Google Scholar 

  • E. Benedetti G. Maglio R. Palumbo C. Pedone (1973) J. Organomet. Chem. 60 189

    Google Scholar 

  • R.J. Puddephatt (1983) Chem. Soc. Rev. 12 99

    Google Scholar 

  • B. Chaudret B. Delavaux R. Poilblanc (1988) Coord. Chem. Rev. 86 191

    Google Scholar 

  • S.O. Grim (1980) E.D.Walton, Inorg. Chem. 19 1982

    Google Scholar 

  • D.E. Berry J. Browning K.R. Dixon R.W. Hilts (1988) Can. J. Chem. 66 1272

    Google Scholar 

  • E.W. Ainscough, A.H. Brodie and A.R. Furness, J. Chem. Soc. Dalton Trans., 2360 (1973).

  • E.W. Ainscough, A.H. Brodie and E. Mentzer, J. Chem. Soc., Dalton Trans., 216 (1973).

  • J. Browning G.W. Bushnell K.R. Dixon A. Pidcock (1983) Inorg. Chem. 22 2226

    Google Scholar 

  • S. Browning K.R. Dixon R. Hilts (1989) Organometallics 8 552

    Google Scholar 

  • G. Exarchos S.C. Nyburg S.D. Robinson (1998) Polyhedron 17 1257

    Google Scholar 

  • Y. Takahashi S. Sakai (1969) J. Organomet. Chem. 16 177

    Google Scholar 

  • R.P. Hughes and J. Powell, Chem. Commun., 275, (1971); R.P. Hughes, J. Organomet. Chem., 30, C45 (1971).

  • P.M. Maitlis, P. Espinet and M.J.H. Russel, in: G. Wilkinson, F.G.A. Stone and E.W. Abel, (Eds), Comprehensive Organometallic Chemistry, Pergamon Press, Oxford 1982, vol. 6, p. 385; W. der Graaf, J. Boersma and G. van Koten, Organometallics, 9, 1479 (1990); M. Formica, A. Musco and R. Pontellini, J. Molec. Catal., 84 239 (1993).

  • G.W. Buschnell D.O. Fielsted S.R. Stobart M.J. Zaworotko S.A.R. Knox K.A. McPherson (1985) Organometallics 4 1107

    Google Scholar 

  • R. Fernandez-Galan B.R. Manzano A. Otero N. Poujaud M. Kubicki (1999) J. Organomet. Chem. 579 321

    Google Scholar 

  • A. Singhal and V.K. Jain, J. Organomet. Chem. 494, 75 (1995); P.D. Hampton, S. Wu, T.M. Alam and J.P. Claverie, Organometallics, 13 2066 (1994).

  • J. Ruiz J. Giner V. Rodriguez G. Lopez J. Casabo E. Molins C. Miravitlles (2000) Polyhedron 19 1627

    Google Scholar 

  • D.D. Perrin, W.L.F. Armarego and D.R. Perrin, Purification of Laboratory Chemicals, 2nd edit., Pergamon, Oxford, 1980.

  • Y. Zhang Z. Yuan J. Puddephatt (1998) Chem. Mater. 10 2293

    Google Scholar 

  • D.W. Allen and B.F. Taylor, J. Chem. Soc., Dalton Trans., 51 (1982).

  • K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 1986, 4th edit., p. 388.

  • R. Redón R. Cramer S. Bernès D. Morales (2001) Polyhedron 20 3119

    Google Scholar 

  • K. Shobatake K. Nakamoto (1970) J. Am. Chem. Soc. 92 11

    Google Scholar 

  • C.G. Sceney R.J. Magee (1974) Inorg. Nucl. Chem. Lett. 10 323

    Google Scholar 

  • E.W. Ainscough and A.M. Brodie, J. Chem. Soc., Dalton Trans., 565 (1977).

  • P.K. Baker S.D. Harris M.C. Durrant R.L. Richards (1996) Polyhedron 15 3595

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science and Arts, Dokuz Eylul University, Izmir, Turkey

    Elif Subasi

  2. Department of Chemistry, University College London, 20 Gordon Street, London, WC1H OAJ, UK

    Graeme Hogarth

Authors
  1. Elif Subasi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Graeme Hogarth
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Subasi, E., Hogarth, G. Synthesis and characterization of η3-allyl palladium(II) complexes with Ph2P(S)CHP(S)Ph2 and OC(CF3)CHCO(C4H3S) co-ligands. Transition Met Chem 30, 372–375 (2005). https://doi.org/10.1007/s11243-004-6963-6

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-004-6963-6

Keywords

Search

Navigation