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Stereochemical, biochemical and ligation behaviour of divalent platinum complexes of sulfur and nitrogen donor agents

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Abstract

Divalent Pt complexes of o-FC6 H4 C(H)NNC(SH)SCH2 Ph(L1H) and o-FC6 H4 C(Me)NNC(SH)SCH2 Ph(L 2H) have been synthesized and characterized thoroughly by analytical data, conductance measurements, molecular weight determinations, magnetic measurements, i.r., electronic, 1H-n.m.r. and 19F-n.m.r. spectral studies. The spectral data are consistent with a square planar geometry around PtIIin which the ligand acts as a neutral bidentate and monobasic bidentate ligand coordinating through nitrogen and sulfur atoms. Ligands and their metal complexes were tested against certain microorganisms to assess their antimicrobial properties and the results are indeed positive.

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Authors and Affiliations

  1. Department of Chemistry, University of Rajasthan, Jaipur, 302004, India

    Nighat Fahmi, Mukesh Kumar Biyala & Ran V. Singh

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  1. Nighat Fahmi
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  2. Mukesh Kumar Biyala
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  3. Ran V. Singh
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Fahmi, N., Biyala, M.K. & Singh, R.V. Stereochemical, biochemical and ligation behaviour of divalent platinum complexes of sulfur and nitrogen donor agents. Transition Metal Chemistry 29, 681–683 (2004). https://doi.org/10.1007/s11243-004-6580-4

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