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Synthesis and characterization of vanadium(V) complexes with α-hydroxyhippuric acid. The X-ray crystal structure of (NBu 4)2[V2O2(O2)2(R-α-hhip) (S-α-hhip)]·5H2O,[α-hhip = α-hydroxyhippurato(2-)]

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Abstract

Peroxovanadium(V) complexes of α-hydroxyhippuric acid (α-H2hhip), M 2[V2O2(O2)2(α-hhip)2]·nH2O, [M=K+ (1), NH4 + (2), NEt 4 + (3), NBu 4 + (4); n=5.5, 3, 8, 5) have been prepared and characterized by elemental analysis, i.r., u.v.–vis. and 51V-n.m.r. spectroscopies and by thermal analysis. The X-ray structure determination of (4) revealed the presence of dinuclear [V2O2(O2)2(R-α-hhip)(S-α-hhip)]2− anions with a planar V2O2 bridging core and seven-coordinated central atoms. The coordination geometry of the vanadium atom is a distorted pentagonal bipyramid.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University, Mlynská dolina, Bratislava, 4 SK-84215, Slovak Republic

    Mohamed Ahmed, Peter Schwendt & Michal Sivá

  2. Laboratory of Functional Genomics and Proteomics, Faculty of Science, Masaryk University, Kotláğská 2, Brno, CZ-61137, Czech Republic

    Jaromín Marek

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  1. Mohamed Ahmed
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  2. Peter Schwendt
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  3. Michal Sivá
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  4. Jaromín Marek
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Ahmed, M., Schwendt, P., Sivá, M. et al. Synthesis and characterization of vanadium(V) complexes with α-hydroxyhippuric acid. The X-ray crystal structure of (NBu 4)2[V2O2(O2)2(R-α-hhip) (S-α-hhip)]·5H2O,[α-hhip = α-hydroxyhippurato(2-)]. Transition Metal Chemistry 29, 675–680 (2004). https://doi.org/10.1007/s11243-004-5363-2

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