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Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands

Abstract

A novel polymeric complex, [Mn(phen)(pdc)] (phen=1,10-phenanthroline, H2pdc=2,5-pyridinedicarboxylic acid) has been synthesized from the hydrothermal reaction system of H2pdc, phen, MnO2, and H2O. [Mn(phen)(pdc)] is characteristic of an edge-sharing dinuclear MnII structure unit bridged by pdc, leading to a 2-D framework whose stacking is based on weak H-bond interaction. The temperature dependence of the magnetic susceptibility for [Mn(phen)(pdc)] indicates antiferromagnetic coupling [J = −2.76(4) cm−1] between the adjacent paramagnetic MnII ions.

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Correspondence to You-Wei Yao.

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Yao, YW., Lin, HX., Sun, XD. et al. Hydrothermal synthesis and crystal structure of a novel 2-D polymeric manganese (II) complex with mixed ligands. Transition Met Chem 30, 294–298 (2005). https://doi.org/10.1007/s11243-004-4578-6

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Keywords

  • Physical Chemistry
  • Crystal Structure
  • Manganese
  • Inorganic Chemistry
  • Catalysis