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Template synthesis in the nickel(II)–thiocarbohydrazide–propanone triple system

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Abstract

The complexing process proceeding in the NiII–thiocarbohydrazide (H2N–H–NC(=S)–NH–NH2)–propanone triple system in EtOH solution and nickel(II)hexacyanoferrate(II) gelatin-immobilized matrix has been studied. It has been found that in the first case, template synthesis leading, as a minimum, to formation of three coordination compounds of NiII with (N,N,S,S)-donor tetradentate ligands having NiL1, NiL2 and NiL3compositions where L1 is 4,6,6-trimethyl-2,3,7,8-tetraazanonen-3-di(thiohydrazide)-1,9, L2 is 4,6,6,12-tetrametyl-1,9-dithio-2,3,7,8,10,11-hexaazatridekadien-3,11-hydrazide-1 and L3 is 2,8,10,10,16-pentamethyl-5,13-dithio-3,4,6,7,11,12,14,15-octaazaheptadekatrien-2,7,15 is observed, whereas in the gelatin-immobilized matrix, a complexing process in the system considered does not occur.

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Authors and Affiliations

  1. Department of Analytical Chemistry, Kazan State Technological University, K.Marx Street 68, 420015, Kazan, Russia

    Oleg V. Mikhailov

  2. Department of Organic Chemistry, Kazan State University, Kremlin Street 18, 420008, Kazan, Russia

    Marina A. Kazymova, Tatyana A. Shumilova & Galina A. Chmutova

  3. Institute of Organic and Physical Chemistry of Kazan Scientific Centre of RAS, Arbusov Street 8, 420012, Kazan, Russia

    Svetlana E. Solovieva

Authors
  1. Oleg V. Mikhailov
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  2. Marina A. Kazymova
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  3. Tatyana A. Shumilova
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  4. Galina A. Chmutova
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  5. Svetlana E. Solovieva
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Mikhailov, O.V., Kazymova, M.A., Shumilova, T.A. et al. Template synthesis in the nickel(II)–thiocarbohydrazide–propanone triple system. Transition Met Chem 30, 299–304 (2005). https://doi.org/10.1007/s11243-004-4577-7

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  • DOI: https://doi.org/10.1007/s11243-004-4577-7

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