Skip to main content
SpringerLink
Log in

Synthesis and characterisation of heterobimetallic N-(hydroxyethyl)-salicylaldiminate–isopropoxide complexes of oxovanadium(V)

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

Soluble heterobimetallic-N-(hydroxyethyl) salicylaldiminate-alkoxide derivatives of the types [VO(L)2{M(OPri) n −1}] [M=Al (2) (n = 3); Ti (3), Zr (4) (n = 4); Nb (5), Ta (6) (n = 5)], [where L represents the dianionic N-(hydroxyethyl) salicylaldiminate group bonded to vanadium in a tridentate fashion involving both the oxygen atoms and azomethine nitrogen], have been prepared by the reactions of insoluble [VO(L)(LH)] (1) with different metal alkoxides in a 1:1 molar ratio in benzene. A monomeric heterobinuclear complex of the type [VO(η3-L)(μ-OPri)2Al(η3-L)] (7) has been prepared by the equimolar reaction of [VO(η3-L)(μ-OPri)]2 with [Al(η3-L) (μ-OPri)]2 in benzene. All these complexes have been characterised by elemental analyses, molecular weight measurements, and by spectroscopic (l.r., 1H-, 27Al- and 51V-n.m.r.) studies. The monomeric nature of (1) and (2) has been supported by their FAB-mass spectral studies.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Butler M.J. Clague G.E. Meister (1994) Chem. Rev. 94 625 Occurrence Handle10.1021/cr00027a004

    Article  Google Scholar 

  2. C. Slebodnick B.J. Hamestra V.L. Pecoraro (1997) Struct. Bond. (Berlin) 89 51

    Google Scholar 

  3. Hagen H., Boersma J., Lutz M., Spek A.L., Vankoten G., (2001) Eur. J. Inorg. Chem., 117.

  4. C. Djordjevic G.L. Wampler (1985) J Inorg. Biochem 25 51 Occurrence Handle10.1016/0162-0134(85)83007-5 Occurrence Handle3850106

    Article  PubMed  Google Scholar 

  5. J.H. McNeil V.G. Yuen Hoveyda H.R C. Orvig (1992) J. Med. Chem. 35 1489 Occurrence Handle10.1021/jm00086a020 Occurrence Handle1573642

    Article  PubMed  Google Scholar 

  6. K.H. Thompson J.H. McNeil C. Orvig (1999) Inorg. Chem. 38 2288 Occurrence Handle10.1021/ic990460x

    Article  Google Scholar 

  7. D.C. Crans J.J. Smee E. Gaidamauskas L. Yang (2004) Chem. Rev. 104 849 Occurrence Handle10.1021/cr020607t Occurrence Handle14871144

    Article  PubMed  Google Scholar 

  8. J.A. Bonadies C.J. Carrano (1986) Inorg. Chem. 25 4358 Occurrence Handle10.1021/ic00244a015

    Article  Google Scholar 

  9. D.C. Fisher Barclay-Peet S.J. C.A. Balfe K.N. Raymond (1989) lnorg Chem 28 4399 Occurrence Handle10.1021/ic00323a023

    Article  Google Scholar 

  10. Cornman C.R G.J. Colpas J.D. Hoeschele J. Kampf V.L. Pecoraro (1992) J. Am. Chem. Soc. 114 9925 Occurrence Handle10.1021/ja00051a026

    Article  Google Scholar 

  11. R. Dinda P. Sengupta S. Ghos C.W. T.Mak (2002) lnorg. Chem. 41 1684 Occurrence Handle10.1021/ic010865t

    Article  Google Scholar 

  12. S.K. Dutta S. Samanta D. Ghosh R.J. Butcher M. Chaudhury (2002) Inorg. Chem. 41 5555 Occurrence Handle10.1021/ic0200895 Occurrence Handle12377053

    Article  PubMed  Google Scholar 

  13. D.C. Bradley R.C. Mehrotra I.P. Rothwel A. Singh Alkoxo (2001) Aryloxo Derivatives of Metals Academic Press London

    Google Scholar 

  14. F. Wolf C. Lorber R. Choukroun B. Donnadieu (2003) Inorg Chem 42 7839 Occurrence Handle10.1021/ic034742f Occurrence Handle14632499

    Article  PubMed  Google Scholar 

  15. R.S. Ghadwal M. Sharma A. Singh R.C. Mehrotra (2004) Transit. Met. Chem. 29 419 Occurrence Handle10.1023/B:TMCH.0000027460.70418.98

    Article  Google Scholar 

  16. A. Singh R.C. Mehrotra (2004) Coord Chem Rev 248 101 Occurrence Handle10.1016/j.cct.2003.09.004

    Article  Google Scholar 

  17. H. Zheng M.W. Colby J.D. Mackenzie (1988) NoChapterTitle C.J. Brinker D.E. Clark D.R. Ulrich (Eds) Better Ceramics Through Chemistry III Mater. Res. Soc. Pittsburgh, PA 537

    Google Scholar 

  18. F. Babonneau A. Leaustic J. Livage (1988) NoChapterTitle C.J. Brinker D.E. Clark D.R. Ulrich (Eds) Better Ceramics Through Chemistry III Mater. Res. Soc Pittsburgh, PA 317

    Google Scholar 

  19. C. Sanchez J. Livage Henry M F. Babonneau (1988) J. Non-Cryst. Solids. 100 65 Occurrence Handle10.1016/0022-3093(88)90007-5

    Article  Google Scholar 

  20. Takahashi Y., Naganawa H., Yogyo-Kyokaishi: 95, 1107 (1987); Chem. Abstr., 107, 241421w (1987).

  21. Takahashi Y., Niwa K., Kobayashi K., Matsuki M., Yogyo-Kyokaishi. 95, 942 (1987); Chem. Abstr., 107, 203776h (1987).

  22. H. Funk W. Weiss (1958) Z. Anorg. Allg. Chem. 296 36 Occurrence Handle10.1002/zaac.19582960107

    Article  Google Scholar 

  23. L.M. Brown K.S. Mazdiyasni (1970) Inorg. Chem. 9 2783 Occurrence Handle10.1021/ic50092a023

    Article  Google Scholar 

  24. J. Nelle’s, Brit Patent, 512452 (1939); Chem. Abstr., 3764 (1940).

  25. D.C. Bradley W. Wardlaw (1950) Nature 165 75

    Google Scholar 

  26. Bradley D.C., Chakravarti B.N., Chatterjee A.K., Wardlaw W., Whitley A., (1958) J Chem. Soc., 99.

  27. L.W. Daasch U.E. Hanninen (1950) J Am Chem Soc 72 3673 Occurrence Handle10.1021/ja01164a096

    Article  Google Scholar 

  28. R.K. Mittal R.C. Mehrotra (1965) Z. Anorg. Allg. Chem. 209 405

    Google Scholar 

  29. A.I. Vogel (1978) A Text Book of Quantitative Inorganic Analysis Longmann London

    Google Scholar 

  30. J. Fabian M. Legrand P. Poirier (1956) Bull. Soc Chim Fr 23 1499

    Google Scholar 

  31. J.E. Kavoic (1967) Spectrochim Acta 23 183

    Google Scholar 

  32. K.L. Chawla P. Prashar J.P. Tondon (1972) J. Indian Chem. Soc. 49 553

    Google Scholar 

  33. H. Zeiss M. Tsutsui (1953) J. Am. Chem. Soc. 75 897 Occurrence Handle10.1021/ja01100a036

    Article  Google Scholar 

  34. C.J. Carrano J.A. Bonadies (1986) J. Am. Chem. Soc. 108 4088 Occurrence Handle10.1021/ja00274a038

    Article  Google Scholar 

  35. S. Holmes C.J. Carrano (1991) Inorg. Chem. 30 1231

    Google Scholar 

  36. M. Mohan S.M. Holmes R.J. Butcher J.P. Jasinki C.J. Carrano (1992) Inorg. Chem. 31 2029

    Google Scholar 

  37. C. Weeks Y. Song M. Suzuki N.A. Chernova P.Y. Zavalij M.S. Whittingham (2003) J Mater Chem 13 1420

    Google Scholar 

  38. Barraclough C.G., Bradley D.C., Lewis J., Thomas I.M., (1961). J. Chem. Soc. 2601.

  39. K.K. Rajak S. Mondal S.P. Rath (2000) Polyhedron 19 931

    Google Scholar 

  40. Gurian P.L., Cheathan L.K., Ziller J.W., Barron A.R., (1991) Chem J., Soc., Dalton Trans., 1449.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Rajasthan, Jaipur, 302 004, India

    Rajendra Singh Ghadwal, Anirudh Singh & Ram C. Mehrotra

Authors
  1. Rajendra Singh Ghadwal
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Anirudh Singh
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ram C. Mehrotra
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ghadwal, R.S., Singh, A. & Mehrotra, R.C. Synthesis and characterisation of heterobimetallic N-(hydroxyethyl)-salicylaldiminate–isopropoxide complexes of oxovanadium(V). Transition Met Chem 30, 268–272 (2005). https://doi.org/10.1007/s11243-004-3766-8

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11243-004-3766-8

Keywords

Search

Navigation