Skip to main content
Log in

Three-Phase Oil Relative Permeability in Water-Wet Media: A Comprehensive Study

  • Published:
Transport in Porous Media Aims and scope Submit manuscript

Abstract

We report experimental three-phase oil relative permeability in two water-wet media (a sandpack and a Berea sandstone core) along different saturation paths. Three oils with different viscosities, compositions, and spreading coefficients were used in the measurements. The data show that oil relative permeability can vary significantly along different saturation paths. Most importantly, we find that despite the significant (orders of magnitude) variation of oil relative permeability along different saturation paths, the oil relative permeability in each medium can be collapsed into a single relative permeability curve, once they are plotted as a function of mobile oil saturation. However, this collapsed curve varies depending on the porous media. We show that the same behavior occurs in the relative permeability data published over the past 50 years. These observations indicate that the key factor in differences between oil permeabilities in the same porous media is changes in the residual oil saturation. We examine the performance of most commonly used relative permeability models, i.e., Corey, Saturation-Weighted Interpolation (SWI), and Stone against our data. Given the importance of residual oil saturation, we fit the experimental data along different saturation paths by treating the residual oil saturation in these models as the fitting parameter while keeping the other parameters constant. We find that the Corey and SWI models fit the data very well while the Stone model performs poorly at low saturations. We find that residual oil saturation is a nonlinear function of gas/water saturation as opposed to linear relationship previously suggested by others.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13
Fig. 14
Fig. 15
Fig. 16
Fig. 17
Fig. 18

Similar content being viewed by others

Abbreviations

C :

Fitting constant, dimensionless

\(C_\mathrm{s}\) :

Spreading coefficient, N/m

\(k_\mathrm{ri} \) :

Relative permeability to phase i, dimensionless

\(k_\mathrm{ro\left( g \right) }\) :

Two-phase oil relative permeability in oil/gas system, dimensionless

\(k_\mathrm{ro\left( w \right) }\) :

Two-phase oil relative permeability in oil/water system, dimensionless

\(k_\mathrm{ro(wr)}\) :

Two-phase oil relative permeability at residual water saturation, dimensionless

\(n_\mathrm{i} \) :

Phase i exponent for relative permeability, dimensionless

\(n_\mathrm{krog}\) :

Oil exponent of gas/oil relative permeability curve, dimensionless

\(n_\mathrm{krow}\) :

Oil exponent of oil/water relative permeability curve, dimensionless

\(S_\mathrm{i} \) :

Saturation of phase i, dimensionless

\(S_\mathrm{gr} \) :

Residual gas saturation, dimensionless

\(S_\mathrm{om} \) :

Three-phase residual oil saturation, dimensionless

\(S_\mathrm{or} \) :

Residual oil saturation, dimensionless

\(S_\mathrm{wr} \) :

Residual water saturation, dimensionless

i:

Phase

g:

Gas

o:

Oil

w:

Water

References

  • Alizadeh, A.H., Piri, M.: The effect of saturation history on three-phase relative permeability: an experimental study. Water Resour. Res. 50(2), 1636–1664 (2014a). doi:10.1002/2013WR014914

    Article  Google Scholar 

  • Alizadeh, A.H., Piri, M.: Three-phase flow in porous media: a review of experimental studies on relative permeability. Rev. Geophys. 52(3), 468–521 (2014b). doi:10.1002/2013RG000433

    Article  Google Scholar 

  • Aziz, K., Settari, A.: Petroleum Reservoir Simulation. Chapman and Hall, London (1979)

    Google Scholar 

  • Baker, L. E.: Three-Phase Relative Permeability Correlations. In SPE Enhanced Oil Recovery Symposium, Vol. SPE-17369-MS, (1988)

  • Blunt, M. J., Fenwick, D. H., Zhou, D.: What Determines Residual Oil Saturation in Three-Phase Flow? In SPE-27816-MS (1994). doi:10.2118/27816-MS

  • Blunt, M.J.: An empirical model for three-phase relative permeability. SPE J. 5(04), 435–445 (2000)

    Article  Google Scholar 

  • Brooks, R.H., Corey, A.T.: Hydraulic Properties of Porous Media. Colorado State University, Hydrology Papers (1964)

  • Chaudhary, K., Cardenas, M.B., Wolfe, W.W., Maisano, J.A., Ketcham, R.A., Bennett, P.C.: Pore-scale trapping of supercritical CO2 and the role of grain wettability and shape. Geophys. Res. Lett. 40(15), 3878–3882 (2013). doi:10.1002/grl.50658

    Article  Google Scholar 

  • Dehghanpour, H.: Measurement and modeling of three-phase oil relative permeability. PhD Dissertation. The University of Texas at Austin (2011)

  • Dehghanpour, H., DiCarlo, D.: A comparative study of transient and steady-state three-phase oil permeability. J. Can. Pet. Technol. 52(1), 54–63 (2013a)

    Article  Google Scholar 

  • Dehghanpour, H., DiCarlo, D.A.: Drainage of capillary-trapped oil by an immiscible gas: impact of transient and steady-state water displacement on three-phase oil permeability. Trans. Porous Media 100(2), 297–319 (2013b). doi:10.1007/s11242-013-0217-z

  • Dehghanpour, H., DiCarlo, D.A., Aminzadeh, B., Mirzaei Galeh-Kalaei, M.: Two-Phase and Three-Phase Saturation Routes and Relative Permeability During Fast Drainage. In SPE-129962-MS, (2010). doi:10.2118/129962-MS

  • Dehghanpour, H., Aminzadeh, B., Mirzaei, M., DiCarlo, D.A.: Flow coupling during three-phase gravity drainage. Phys. Rev. E 83(6), 065302 (2011)

    Article  Google Scholar 

  • Delshad, M., Delshad, M., Pope, G. A., Lake, L. W.: Two- and Three-Phase Relative Permeabilities of Micellar Fluids. SPE-13581-PA, (1987). doi:10.2118/13581-PA

  • Delshad, M., Pope, G.A.: Comparison of the three-phase oil relative permeability models. Transp. Porous Media 4(1), 59–83 (1989)

    Article  Google Scholar 

  • DiCarlo, D.A., Sahni, A., Blunt, M.J.: Three-phase relative permeability of water-wet oil-wet and mixed-wet sandpacks. SPE J. 5(01), 82–91 (2000a)

    Article  Google Scholar 

  • DiCarlo, D.A., Sahni, A., Blunt, M.J.: The effect of wettability on three-phase relative permeability. Transp. Porous Media 39(3), 347–366 (2000b)

    Article  Google Scholar 

  • Dria, D. E., Pope, G. A., Sepehrnoori, K.: Three-Phase Gas/Oil/Brine Relative Permeabilities Measured Under CO2 Flooding Conditions. SPE-20184-PA, (1993). doi:10.2118/20184-PA

  • Eleri, O.O., Graue, A., Skauge, A., Larsen, J.A.: Calculation of three-Phase Relative Permeabilities from Displacement Experiments with Measurements of In-Situ Saturation. In Soc. Core Anal. Int. Symp, San Francisco (1995b)

  • Eleri, O. O., Graue, A., Skauge, A.: Steady-State and Unsteady-State Two-Phase Relative Permeability Hysteresis and Measurements of Three-Phase Relative Permeabilities Using Imaging Techniques. In SPE-30764-MS, (1995a)

  • Fayers, F. J.: Extension of Stone’s Method 1 and Conditions for Real Characteristics in Three-Phase Flow. SPE-16965-PA, (1989). doi:10.2118/16965-PA

  • Fayers, F.J., Matthews, J.D.: Evaluation of normalized stone’s methods for estimating three-phase relative permeabilities. SPE J. 24(02), 224–232 (1984)

    Article  Google Scholar 

  • Fenwick, D. H., Blunt, M. J.: Network Modeling of Three-Phase Flow in Porous Media. SPE-38881-PA, (1998). doi:10.2118/38881-PA

  • Grader, A. S., O’Meara Jr, D. J.: Dynamic Displacement Measurements of Three-Phase Relative Permeabilities Using Three Immiscible Liquids. In SPE-18293-MS, (1988)

  • Hosain, A.: Three-Phase Relative Permeability Measurements. Master’s Thesis, University of Birmingham, UK, (1961)

  • Hustad, O. S., Holt, T.: Gravity Stable Displacement of Oil By Hydrocarbon Gas After Waterflooding. In SPE-24116-MS, (1992). doi:10.2118/24116-MS

  • Jerauld, G.R.: General three-phase relative permeability model for Prudhoe Bay. SPE Reserv. Eng. 12(4), 255–263 (1997)

    Article  Google Scholar 

  • Johnson, E. F., Bossler, D. P., Naumann, V. O.: Calculation of Relative Permeability from Displacement Experiments. Petroleum Transactions, AIME, SPE-1023-G 216, 370–72 (1959)

  • Juanes, R., Patzek, T. W.: Relative Permeabilities in Co-Current Three-Phase Displacements with Gravity. In SPE-83445-MS, (2003). doi:10.2118/83445-MS

  • Juanes, R., Patzek, T. W.: Three-Phase Displacement Theory: An Improved Description of Relative Permeabilities. In SPE-77539-MS, (2002). doi:10.2118/77539-MS

  • Juanes, R., Spiteri, E.J., Orr, F.M., Blunt, M.J.: Impact of relative permeability hysteresis on geological CO2 storage. Water Resour. Res. 42(12), W12418 (2006). doi:10.1029/2005WR004806

    Article  Google Scholar 

  • Juanes, R., Patzek, T.W.: Relative permeabilities for strictly hyperbolic models of three-phase flow in porous media. Transp. Porous Media 57(2), 125–152 (2004). doi:10.1023/B:TIPM.0000038251.10002.5e

    Article  Google Scholar 

  • Kianinejad, A., Aminzadeh, B., Chen, X., DiCarlo, D. A.: Three-Phase Relative Permeabilities as a Function of Flow History. In SPE-169083-MS. SPE Improved Oil Recovery Symposium, 12–16 April, Tulsa, Oklahoma, USA, (2014). doi:10.2118/169083-MS

  • Kianinejad, A., Chen, X., DiCarlo, D.A.: The effect of saturation path on three-phase relative permeability. Water Resour. Res. (2015a). doi:10.1002/2015WR017185

  • Kianinejad, A., Chen, X., DiCarlo, D. A.: Three-Phase Relative Permeability in Consolidated Media. In SPE-175129-MS. Houston, Texas, (2015b). doi:10.2118/175129-MS

  • Lake, L. W.: Enhanced Oil Recovery. Society of Petroleum Engineers (1989)

  • Larsen, J. A., Skauge, A.: Methodology for Numerical Simulation With Cycle-Dependent Relative Permeabilities. SPE-38456-PA, (1998). doi:10.2118/38456-PA

  • Mavaddat, M., Riahi, S.: A molecular structure based model for predicting optimal salinity of anionic surfactants. Fluid Phase Equilib. 409, 354–360 (2016). doi:10.1016/j.fluid.2015.10.010

    Article  Google Scholar 

  • Mohsenzadeh, A., Nabipour, M., Asadizadeh, S., Nekouie, M., Ameri, A., Ayatollahi, S.: Experimental investigation of different steam injection scenarios during SAGD process. Spec. Top. Rev. Porous Media: An Int. J. 2(4), 283–291 (2011). doi:10.1615/SpecialTopicsRevPorousMedia.v2.i4.30

    Article  Google Scholar 

  • Muqeem, M. A., Bentsen, R. G., Maini, B. B.: An Improved Steady-State Technique for Three-Phase Relative Permeability Measurements. In PETSOC-93-03, (1993). doi:10.2118/93-03

  • Naylor, P., Sargent, N.C., Crosbie, A.J., Tilsed, A.P., Goodyear, S.G.: Gravity drainage during gas injection. Pet. Geosci. 2(1), 69–74 (1996)

    Article  Google Scholar 

  • Oak, M. J., Baker, L. E., Thomas, D. C.: Three-Phase Relative Permeability of Berea Sandstone. SPE-17370-PA, (1990). doi:10.2118/17370-PA

  • Oak, M. J.: Three-Phase Relative Permeability of Intermediate-Wet Berea Sandstone. In SPE-22599-MS, (1991)

  • Oak, M. J.: Three-phase relative permeability of water-Wet Berea. In SPE-20183-MS, (1990)

  • Oren, P. E., Billiotte, J., Pinczewski, W. V.: Mobilization of Waterflood Residual Oil by Gas Injection for Water-Wet Conditions. SPE-20185-PA, (1992). doi:10.2118/20185-PA

  • Pejic, D., Maini, B. B.: Three-Phase Relative Permeability of Petroleum Reservoirs. In SPE-81021-MS, (2003). doi:10.2118/81021-MS

  • Pini, R., Krevor, S.C.M., Benson, S.M.: Capillary pressure and heterogeneity for the CO2/water system in sandstone rocks at reservoir conditions. Adv. Water Resour. 38, 48–59 (2012). doi:10.1016/j.advwatres.2011.12.007

    Article  Google Scholar 

  • Piri, M., Blunt, M.J.: Three-dimensional mixed-wet random pore-scale network modeling of two-and three-phase flow in porous media II. Results. Phys. Rev. E 71(2), 026302 (2005a)

    Article  Google Scholar 

  • Piri, M., Blunt, M.J.: Three-dimensional mixed-wet random pore-scale network modeling of two-and three-phase flow in porous media I. Model description. Phys. Rev. E 71(2), 026301 (2005b)

    Article  Google Scholar 

  • Pope, G. A., Wu, W., Narayanaswamy, G., Delshad, M., Sharma, M., Wang, P.: Modeling relative permeability effects in gas-condensate reservoirs. In SPE-49266-MS, (1998). doi:10.2118/49266-MS

  • Sahni, A., Burger, J., Blunt, M. J.: Measurement of Three Phase Relative Permeability during Gravity Drainage Using CT. In SPE-39655-MS, (1998)

  • Saraf, D. N., Batycky, J. P., Jackson, C. H., Fisher, D. B.: An Experimental Investigation of Three-Phase Flow of Water-Oil-Gas Mixtures through Water-Wet Sandstones. In SPE-10761-MS, (1982)

  • Sarem, A.M.: Three-phase relative permeability measurements by unsteady-state method. SPE J. 6(03), 199–205 (1966)

    Article  Google Scholar 

  • Shahverdi, H., Sohrabi, M.: An Improved Three-Phase Relative Permeability and Hysteresis Model for the Simulation of a Water-Alternating-Gas Injection. SPE-152218-PA, (2013). doi:10.2118/152218-PA

  • Spiteri, E. J., Juanes, R., Blunt, M. J., Orr, F. M.: A New Model of Trapping and Relative Permeability Hysteresis for All Wettability Characteristics. SPE-96448-PA, (2008). doi:10.2118/96448-PA

  • Stone, H. L.: Probability model for estimating three-phase relative permeability. SPE-2116-PA, (1970). doi:10.2118/2116-PA

  • Zhang, J., Nguyen, Q. P., Flaaten, A., Pope, G. A.: Mechanisms of enhanced natural imbibition with novel chemicals. SPE-113453-PA, (2009). doi:10.2118/113453-PA

  • Zhou, D., Blunt, M.: Effect of spreading coefficient on the distribution of light non-aqueous phase liquid in the subsurface. J. Contam. Hydrol. 25(1), 1–19 (1997). doi:10.1016/S0169-7722(96)00025-3

    Article  Google Scholar 

Download references

Acknowledgments

The authors acknowledge the financial support of the gas enhanced oil recovery joint industry project (JIP) at the University of Texas at Austin. The authors also would like to thank Xiongyu Chen and Paul Jordan for their helps during the experiments. The relative permeability versus saturation data are available upon request by emailing David A. DiCarlo or Amir Kianinejad at dicarlo@mail.utexas.edu or kianinejad.amir@utexas.edu.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Amir Kianinejad.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kianinejad, A., DiCarlo, D.A. Three-Phase Oil Relative Permeability in Water-Wet Media: A Comprehensive Study. Transp Porous Med 112, 665–687 (2016). https://doi.org/10.1007/s11242-016-0669-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11242-016-0669-z

Keywords

Navigation