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Nanodispersed VOx/SiO2 Catalysts of Partial Oxidation of Paraffin Hydrocarbons

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Theoretical and Experimental Chemistry Aims and scope

VOx/SiO2 with different V/Si atomic ratios have been synthesized by hydrothermal method from alkoxides of vanadium and silicon compounds. The prepared samples are characterized by high specific surface area (300-700 m2/g), uniform nanodispersed distribution of vanadia in silica matrix, the absence of crystalline phases, and the absence of the band typical for V=O bond in the Raman spectra. High activity and selectivity of the synthesized catalysts in oxidation of methane to formaldehyde, oxy-dehydrogenation of propane and n-butane have been established.

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Authors and Affiliations

  1. Institute for Sorption and Problems of Endoecology, NAS of Ukraine, Kyiv, Ukraine

    V. O. Zazhigalov, S. B. Grinenko, I. V. Bacherikova & O. A. Diyuk

Authors
  1. V. O. Zazhigalov
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  2. S. B. Grinenko
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  3. I. V. Bacherikova
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  4. O. A. Diyuk
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Correspondence to V. O. Zazhigalov.

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S. B. Grinenko is deceased

Translated from Teoretychna ta Eksperymentalna Khimiya, Vol. 58, No. 4, pp. 236-242, July-August, 2022.

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Zazhigalov, V.O., Grinenko, S.B., Bacherikova, I.V. et al. Nanodispersed VOx/SiO2 Catalysts of Partial Oxidation of Paraffin Hydrocarbons. Theor Exp Chem 58, 261–268 (2022). https://doi.org/10.1007/s11237-022-09743-4

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  • DOI: https://doi.org/10.1007/s11237-022-09743-4

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