Skip to main content

Solid Phase Luminescence and Thermal Transformations of Palladium(II) Complexes with 3-(2-Pyridyl)-1,2,4-Triazoles

Theoretical and Experimental Chemistry volume 57, pages 358–365 (2021)Cite this article

The thermal behavior and luminescent properties of palladium(II) Pd(LR)2 complexes with 3-(2-pyridyl)-5-R-1,2,4-triazoles (LR , where R = H, Ph, Me) in cristalline state were studied. Analysis of the stationary and time-resolved Pd(LMe)2 photoluminescence spectra showed that the introduction of electron–donor methyl substituent into a coordinated ligand is accompanied by emission in the green range of the spectrum (fluorescence, λmax = 442 nm). Molecule aggregation in Pd(LH)2 and Pd(LPh)2 complexes leads to a bathochromic shift of emission (phosphorescence, 𝜆max = 712 and 691 nm).

This is a preview of subscription content, access via your institution.

Access options

Buy single article

Instant access to the full article PDF.

USD 39.95

Price includes VAT (USA)
Tax calculation will be finalised during checkout.

Fig. 1
Fig. 2
Fig. 3

References

  1. S. Gosiewska, S. H. Martinez, M. Lutz, et al., Eur. J. Inorg. Chem., 2006, No. 22, 4600-4607 (2006).

    Article  Google Scholar 

  2. B. V. Zakharchenko, D. M. Khomenko, R. O. Doroshchuk, et al., New J. Chem., 43, No. 27, 10973-10984 (2019).

    CAS  Article  Google Scholar 

  3. O. Cuzan-Munteanu, D. Sirbu, M. Giorgi, et al., Eur. J. Inorg. Chem., 2020, No. 10, 813-822 (2020).

    CAS  Article  Google Scholar 

  4. C. R. Wen, Y. J. Wang, and C. H. Wang, Chem. Mater., 17, No. 7, 1646-1654 (2005).

    CAS  Article  Google Scholar 

  5. P. K. Chow, C. Ma, and W. P. To, Angew. Chem. Int. Ed., 52, No. 45, 11775-11779 (2013).

    CAS  Article  Google Scholar 

  6. T. Fleetham, L.Y. Ji, L. Huang, et al., Chem. Sci., 8, No. 12, 7983-7990 (2017).

    CAS  Article  Google Scholar 

  7. Z.-Q. Zhu, C.-D. Park, K. Klimes, and J. Li, Adv. Opt. Mater., 7, No. 16, 801518 (2019).

    Google Scholar 

  8. T. Kitamori, D. Yoo, K. Iijima, et al., ACS Appl. Electron. Mater., 1, No. 8, 1633-1640 (2019).

    CAS  Article  Google Scholar 

  9. C. Cuerva, J. A. Campo, M. Cano, and R. Schmidt, Dalton Trans., 46, No. 1, 96-105 (2017).

    CAS  Article  Google Scholar 

  10. C. Cuerva, J. A. Campo, M. Cano, et al., Inorg. Chem., 55, No. 14, 6995-7002 (2016).

    CAS  Article  Google Scholar 

  11. L. Bruckmann, W. Tyrra, S. Stucky, and S. Mathur, Inorg. Chem., 51, No. 1, 536-542 (2011).

    Article  Google Scholar 

  12. K. Assim, M. Melzer, M. Korb, et al., RSC Adv., 6, No. 104, 102557-102569 (2016).

    CAS  Article  Google Scholar 

  13. A. Diaz-Ortiz, P. Prieto, J. R. Carrillo, et al., Curr. Org. Chem., 19, No. 7, 568-584 (2015).

    CAS  Article  Google Scholar 

  14. R. Kharb, P. C. Sharma, and M. S. Yar, J. Enz. Inhib. Med. Chem., 26, No. 1, 1-21 (2011).

    CAS  Article  Google Scholar 

  15. H. A. M. El-Sherief, B. G. M. Youssif, S. N. A. Bukhari, et al., Bioorg. Chem., 76, 314-325 (2017).

    Article  Google Scholar 

  16. B. V. Zakharchenko, D. M. Khomenko, R. O. Doroshchuk, et al., Chem. Pap., 71, No. 10, 2003-2009 (2017).

    CAS  Article  Google Scholar 

  17. CrysAlisPro Software system, version 1.171.40_64.67, Rigaku Corporation, Oxford, UK (2015).

  18. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, et al., J. Appl. Crystallogr., 42, 339-341 (2009).

    CAS  Article  Google Scholar 

  19. G. M. Sheldrick, Acta Crystallogr. A, 71, 3-8 (2015).

    Article  Google Scholar 

  20. G. M. Sheldrick, Acta Crystallogr. C, 71, 3-8 (2015).

    Article  Google Scholar 

  21. L. E. Sarto, W. P. D. Badary, and E. P. Gois, J. Mol. Struct., 1204, 127549 (2020).

    CAS  Article  Google Scholar 

  22. N. S. Nikolaeva, N. V. Kuratieva, E. S. Vikulova, et al., Polyhedron, 171, 455-463 (2019).

    CAS  Article  Google Scholar 

  23. A. D. Shushanyan, N. S. Nikolaeva, E. S. Vikulova, et al., J. Therm. Anal. Calorim., 136, 2341-2352 (2019).

    CAS  Article  Google Scholar 

  24. M. D. Santana, L. Lopez-Banet, and G. Sanchez, Dalton Trans., 45, No. 20, 8601-8613 (2016).

    CAS  Article  Google Scholar 

  25. M. Micutz, M. Ilis, and T. Staicu, Dalton Trans., 43, No. 3, 1151-1161 (2014).

    CAS  Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Taras Shevchenko Kyiv National University, Kyiv, Ukraine

    B. V. Zakharchenko, D. M. Khomenko, R. O. Doroshchuk, I. V. Raspertova, I. V. Fesych, V. S. Starova & R. D. Lampeka

  2. A. V. Bogatsky Physico-Chemical Institute, NAS of Ukraine, Odesa, Ukraine

    N. V. Rusakova & S. S. Smola

  3. “Petru Poni” Institute of Macromolecular Chemistry, Iasi, Romania

    S. Shova

Authors
  1. B. V. Zakharchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. M. Khomenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. O. Doroshchuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. V. Raspertova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. V. Fesych
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. S. Starova
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. N. V. Rusakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. S. S. Smola
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. S. Shova
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. R. D. Lampeka
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. V. Zakharchenko.

Additional information

Translated from Teoretychna ta Eksperymentalna Khimiya, Vol. 57, No. 5, pp. 307-313, September-October, 2021.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Zakharchenko, B.V., Khomenko, D.M., Doroshchuk, R.O. et al. Solid Phase Luminescence and Thermal Transformations of Palladium(II) Complexes with 3-(2-Pyridyl)-1,2,4-Triazoles. Theor Exp Chem 57, 358–365 (2021). https://doi.org/10.1007/s11237-021-09705-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11237-021-09705-2

Keywords

  • 1,2,4-triazoles
  • palladium(II) coordination compounds
  • luminescent properties
  • CVD precursors
  • X-ray diffraction analysis