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Effect of Polyethylene Glycol on the Structure and Catalytic Properties of 1% Pd/ZnO Nanocomposites in the Selective Hydrogenation of Acetylenic Alcohols

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Theoretical and Experimental Chemistry Aims and scope

It is shown that modification of zinc oxide with polyethylene glycol leads to an increase in the catalytic activity of 1% Pd/ZnO nanocomposites in the low-temperature selective hydrogenation of acetylenic alcohols. This effect is due to the formation of palladium nanoparticles 2-4 nm in size in the polymer layer attached to the surface of the zinc oxide.

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The work was carried out with financial support from the State Institution Committee of Science, Ministry of Education and Science, Kazakhstan Republic (grant Nos. AR05133114, AR05130377).

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Authors and Affiliations

  1. D. V. Sokolskiy Institute of Fuel, Catalysis and Electrochemistry, Kunayev St., Almaty, Kazakhstan, 142

    A. K. Zharmagambetova, E. T. Talgatov, A. S. Auyezkhanova & N. Zh. Tumabayev

  2. Satbayev University, Satbayev St., 22a, Almaty, Kazakhstan

    Kh. Rafikova

  3. Kazakh Academy of Architecture and Civil Engineering, Ryskulbekov St., Almaty, Kazakhstan, 28

    A. T. Zamanbekova

Authors
  1. A. K. Zharmagambetova
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  2. E. T. Talgatov
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  3. A. S. Auyezkhanova
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  4. Kh. Rafikova
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  5. A. T. Zamanbekova
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  6. N. Zh. Tumabayev
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Corresponding author

Correspondence to A. K. Zharmagambetova.

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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 54, No. 4, pp. 244-250, July-August, 2018.

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Zharmagambetova, A.K., Talgatov, E.T., Auyezkhanova, A.S. et al. Effect of Polyethylene Glycol on the Structure and Catalytic Properties of 1% Pd/ZnO Nanocomposites in the Selective Hydrogenation of Acetylenic Alcohols. Theor Exp Chem 54, 265–273 (2018). https://doi.org/10.1007/s11237-018-9572-8

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  • DOI: https://doi.org/10.1007/s11237-018-9572-8

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