The morphology of hierarchical zeolite nanocrystals with MOR, BEA, MFI, and MTW topology has a significant effect on the accessibility of the Brønsted and Lewis acid centers, the concentration and strength of which are determined by the type and concentration of the heteroelement B, Al, Ga, Ti, Sn, or Zr in the initial reaction mixture. Nanoparticles (0D), nanorods (1D), and nanolayers (2D) of hierarchical zeolites exhibit different catalytic activity in fine organic synthesis.
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The work was carried out with partial financial support from a target program of scientific investigations of the National Academy of Sciences of Ukraine “New functional compounds and materials of chemical production.”
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 54, No. 2, pp. 126-132, March-April, 2018.
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Shvets, O.V., Konysheva, K.M. & Kurmach, M.M. Morphology and Catalytic Properties of Hierarchical Zeolites with MOR, BEA, MFI, and MTW Topology. Theor Exp Chem 54, 138–145 (2018). https://doi.org/10.1007/s11237-018-9557-7
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DOI: https://doi.org/10.1007/s11237-018-9557-7