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Effect of Acid Site Localization in Sulfonic Resin Amberlyst 15 on its Catalytic Properties in Ethyl tert-butyl Ether Synthesis

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Theoretical and Experimental Chemistry Aims and scope

The role of the localization of acid sites in macroporous sulfonic resin Amberlyst 15 in the synthesis of ethyl tert-butyl ether was investigated. By partial blockage of the acid sites by Na+ cations it was established that internal acid sites are primarily active in the reaction while a side reaction with the formation of tert-butanol takes place at the external acid sites.

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The authors thank V. L. Struzhko for preparing the samples and T. G. Serebrii for carrying out the QE-TD experiment.

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Authors and Affiliations

  1. L. V. Pysarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine

    Yu. N. Kochkin, N. V. Vlasenko & P. E. Strizhak

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  1. Yu. N. Kochkin
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  2. N. V. Vlasenko
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  3. P. E. Strizhak
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Correspondence to Yu. N. Kochkin.

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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 53, No. 2, pp. 128-132, March-April, 2017.

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Kochkin, Y.N., Vlasenko, N.V. & Strizhak, P.E. Effect of Acid Site Localization in Sulfonic Resin Amberlyst 15 on its Catalytic Properties in Ethyl tert-butyl Ether Synthesis. Theor Exp Chem 53, 138–142 (2017). https://doi.org/10.1007/s11237-017-9510-1

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  • DOI: https://doi.org/10.1007/s11237-017-9510-1

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