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Effect of the Composition and Post-Synthesis Heat Treatment on the Electrochemical Characteristics of Polypyrrole/V2O5 Nanocomposites Prepared by a Mechanochemical Method

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Theoretical and Experimental Chemistry Aims and scope

Effects were shown for the composition and post-synthesis heat treatment in an oxygen atmosphere on the electrochemical properties of nanocomposites derived from polypyrrole (PPy) and a V2O5 xerogel with host–guest structure. PPy0.05V2O5 was found to have the highest specific discharge capacity of about 290 mA·h/g and high stability upon prolonged charge-discharge cycling among the PPyxV2O5 nanocomposites prepared (where x = 0.1, 0.05, 0.025). Post-synthesis heat treatment in an oxygen atmosphere leads to oxidation of the reduced portion of the inorganic nanocomposite component and nanostructurization of the composite with formation of nanofibers that facilitate a considerable increase in the specific capacity and stability upon cycling.

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Authors and Affiliations

  1. L. V. Pisarzhevsky Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine

    O. Yu. Posudievsky, O. A. Kozarenko, V. S. Dyadyun, V. G. Koshechko & V. D. Pokhodenko

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  1. O. Yu. Posudievsky
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  2. O. A. Kozarenko
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  3. V. S. Dyadyun
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  4. V. G. Koshechko
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  5. V. D. Pokhodenko
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Correspondence to O. Yu. Posudievsky.

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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 51, No. 3, pp. 156-162, May-June, 2015.

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Posudievsky, O.Y., Kozarenko, O.A., Dyadyun, V.S. et al. Effect of the Composition and Post-Synthesis Heat Treatment on the Electrochemical Characteristics of Polypyrrole/V2O5 Nanocomposites Prepared by a Mechanochemical Method. Theor Exp Chem 51, 163–169 (2015). https://doi.org/10.1007/s11237-015-9411-0

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  • DOI: https://doi.org/10.1007/s11237-015-9411-0

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