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Exchange Interactions in Cobalt(II) and Nickel(II) Complexes Containing M4(μ3-OH)2 Metal Cores with Distorted Rhombic Topology

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Theoretical and Experimental Chemistry Aims and scope

Antiferromagnetic interactions between the Co2+ or Ni2+ ions were found in complexes [(μ3 ‐ L)2Co II5 (μ ‐ OH)2(Piv)7(NO3)] and [(μ3 ‐ L)2(HPiv)Ni II4 (μ3 ‐ OH)2(Piv)4(NO3)2] (Piv– = pivalic acid anion, L = 1,1′-dipyridazinylferrocene) possessing a metal core with distorted rhombic topology M4(μ3-OH)2. In contrast to the case of symmetrical analogs, the signs of all the exchange interaction parameters J were determined unambiguously.

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This work was carried out with the financial support of the Russian Basic Research Fund (Project No. 14-23-00176).

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskiy Prospekt, 31, Moscow, 119991, Russian Federation

    A. E. Goldberg, G. G. Aleksandrov, M. A. Kiskin, A. A. Sidorov & I. L. Eremenko

  2. Institute “International Tomographic Center”, Siberian Branch, Russian Academy of Sciences, Ul. Institutskaya, 3a, Novosibirsk, 630090, Russian Federation

    A. S. Bogomyakov

  3. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, Ukraine

    S. V. Kolotilov

  4. I. Ya. Postovskii Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences, Ul. S. Kovalevskoy, 22, Ekaterinburg, 620041, Russian Federation

    I. A. Utepova & O. N. Chupakhin

Authors
  1. A. E. Goldberg
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  2. G. G. Aleksandrov
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  3. A. S. Bogomyakov
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  4. M. A. Kiskin
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  5. S. V. Kolotilov
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  6. I. A. Utepova
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  7. A. A. Sidorov
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  8. O. N. Chupakhin
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  9. I. L. Eremenko
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Corresponding authors

Correspondence to M. A. Kiskin or S. V. Kolotilov.

Additional information

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 50, No. 6, pp. 360-366, November-December, 2014.

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Goldberg, A.E., Aleksandrov, G.G., Bogomyakov, A.S. et al. Exchange Interactions in Cobalt(II) and Nickel(II) Complexes Containing M4(μ3-OH)2 Metal Cores with Distorted Rhombic Topology. Theor Exp Chem 50, 364–370 (2015). https://doi.org/10.1007/s11237-015-9389-7

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  • DOI: https://doi.org/10.1007/s11237-015-9389-7

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