Skip to main content
SpringerLink
Log in

Adsorption Properties of Porous Materials Based on Macrocyclic Nickel(II) Complexes and Benzenetricarboxylate Relative to Water, Methanol, and Hexane Vapor

  • Published:
Theoretical and Experimental Chemistry Aims and scope

We have shown that varying the substituents in the cationic component of porous crystal compounds formed by azamacrocyclic nickel(II) complexes and the 1,3,5-benzenetricarboxylate anion has a substantial effect on their adsorption behavior relative to water, methane, and n-hexane vapor. The studied compounds are characterized by reversibility of the changes in the crystal lattices during adsorption/desorption, stoichiometry of the reaction with water vapor with relatively low and hydrolytic stability at high humidity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. D. Farrusseng (ed.), Metal–Organic Frameworks: Applications from Catalysis to Gas Storage, Wiley-VCH Verlag, Weinheim (2011).

    Google Scholar 

  2. L. R. MacGillivray, Metal–Organic Frameworks: Design and Application, Wiley-VCH Verlag, Hoboken (2010).

    Book  Google Scholar 

  3. J.-K. Sun, M. Ji, C. Chen, et al., Chem. Commun., 49, No. 16, 1624–1626 (2013).

    Article  CAS  Google Scholar 

  4. L. Yang, S. Kinoshita, T. Yamada, et al., Angew. Chem. Int. Ed., 49, No. 31, 5348–5351 (2010).

    Article  CAS  Google Scholar 

  5. M. Yoon, K. Suh, S. Natarajan, and K. Kim, Angew. Chem. Int. Ed., 52, No. 10, 2688–2700 (2013).

    Article  CAS  Google Scholar 

  6. H. Okawa, A. Shigematsu, M. Sadakiyo, et al., J. Am. Chem. Soc., 131, No. 37, 13516–13522 (2009).

    Article  CAS  Google Scholar 

  7. I. L. Andriichuk, “Crystal structure, redox reactions, and sorption properties of metal-organic framework compounds based on carboxylate azamacrocyclic nickel(II) and copper(II) complexes,” Dissertation in competition for the academic degree of Candidate of Chemical Sciences, Kiev (2009).

  8. T.-B. Lu, H. Xiang, R. L. Luck, et al., CrystEngComm., 3, No. 41, 168–169 (2001).

    Article  Google Scholar 

  9. Ya. D. Lampeka and L. V. Tsymbal, Teor. Éksp. Khim., 40, No. 6, 331–356 (2004). [Theor. Exp. Chem., 40, No. 6, 345–371 (2004) (English translation).]

    Article  CAS  Google Scholar 

  10. X.-R. Meng, D.-C. Zhong, L. Jiang, et al., Cryst. Growth Des., 11, No. 5, 2020–2025 (2011).

    Article  CAS  Google Scholar 

  11. Ya. D. Lampeka, L. V. Tsymbal, A. V. Barna, et al., Dalton Trans., 41, No. 14, 4118–4125 (2012).

    Article  CAS  Google Scholar 

  12. A. L. Spek, “PLATON: A Multipurpose Crystallographic Tool,” v. 1.16, Utrecht University, Utrecht, The Netherlands (2001).

    Google Scholar 

  13. S. Parsons, V. B. Jagaln, A. Harrison, et al., private communication (2006) (cited from search result in Cambridge Structural Database, version V5.34, structure code PELCOZ).

  14. M. M. Dubinin, Abstracts, Sixth Conference on Theoretical Topics in Adsorption [in Russian], Nauka, Moscow (1985), pp. 141–148.

    Google Scholar 

  15. S. Noro, R. Kitaura, S. Kitagawa, et al., Inorg. Chem., 45, No. 22, 8990–8997 (2006).

    Article  CAS  Google Scholar 

  16. C. E. Webster, R. S. Drago, and M. C. Zerner, J. Am. Chem. Soc., 120, No. 22, 5509–5516 (1998).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine

    L. V. Tsymbal, I. L. Andriichuk, P. S. Yaremov, V. G. Ilyin & Ya. D. Lampeka

Authors
  1. L. V. Tsymbal
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. L. Andriichuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. S. Yaremov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. G. Ilyin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Ya. D. Lampeka
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Ya. D. Lampeka.

Additional information

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 49, No. 4, pp. 255–261, July-August, 2013.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tsymbal, L.V., Andriichuk, I.L., Yaremov, P.S. et al. Adsorption Properties of Porous Materials Based on Macrocyclic Nickel(II) Complexes and Benzenetricarboxylate Relative to Water, Methanol, and Hexane Vapor. Theor Exp Chem 49, 270–276 (2013). https://doi.org/10.1007/s11237-013-9326-6

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11237-013-9326-6

Keywords

Search

Navigation