We have studied conversion of methanol to dimethyl ether and hydrocarbons on aluminum oxide and also on H- and phosphoric acid-modified forms of zeolites Y and ZSM-5. We hypothesize that formation of the primary hydrocarbon ethylene is structure-sensitive and depends on the distance between Brønsted acid and Lewis base sites responsible for the reaction.
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 49, No. 1, pp. 55–59, January-February, 2013.
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Abasov, S.I., Babayeva, F.A., Guliyev, B.B. et al. Features of Methanol and Dimethyl Ether Conversion to Hydrocarbons on Modified Zeolites Y and ZSM-5. Theor Exp Chem 49, 58–64 (2013). https://doi.org/10.1007/s11237-013-9295-9
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DOI: https://doi.org/10.1007/s11237-013-9295-9