The possibility of producing olefins from a mixture of carbon monoxide with hydrogen at atmospheric pressure on catalysts containing Fe and MnO2 nanoparticles on inert supports was studied. The differences in the catalytic activity and selectivity are attributed to the different rates of spillover of the weakly bound hydrogen (HI) and also to the rate of jumpover of the CH x radicals from one center to another.
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The powders were produced at the Moscow Academy of Steel and Alloys.
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 49, No. 1, pp. 43-48, January-February, 2013.
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Dementyeva, M.V., Sheshko, T.F. & Serov, Y.M. Synthesis of olefins from CO and H2 at atmospheric pressure on Fe- and MnO2-containing nanosystems. Theor Exp Chem 49, 46–51 (2013). https://doi.org/10.1007/s11237-013-9293-y
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DOI: https://doi.org/10.1007/s11237-013-9293-y