Skip to main content
SpringerLink
Log in

Thermodynamic approach to prediction of the effect of size on nanostructure properties

  • Published:
Theoretical and Experimental Chemistry Aims and scope

Approaches to the prediction of the properties of small particles with diameter down to 1-2 nm are proposed using the Thomson–Kelvin, Clapeyron–Clausius, and Laplace laws as well as the Poynting effect. Particles with minimal dimensions but with a well-formed surface characterized by surface tension were found to be optimal relative to chemical potential.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. G. R. Kosmambetova, P. E. Strizhak, E. M. Moroz, et al., Teor. Éksp. Khim., 43, No. 2, 96–101 (2007). [Theor. Exp. Chem., 43, No. 2, 102–107 (2007) (English translation).]

    Article  CAS  Google Scholar 

  2. I. L. Stolyarchuk, L. Yu. Dolgikh, I. V. Vasilenko, et al., Teor. Éksp. Khim., 48, No. 2, 119–123 (2012). [Theor. Exp. Chem., 48, No. 2, 129–134 (2012) (English translation).]

    Article  CAS  Google Scholar 

  3. I. B. Bychko, E. Yu. Kalishin, and P. E. Strizhak, Teor. Éksp. Khim., 48, No. 3, 179–183 (2012). [Theor. Exp. Chem., 48, No. 3, 194–198 (2012) (English translation).]

    Article  CAS  Google Scholar 

  4. O. A. Boeva, M. O. Sergeev, A. Yu. Antonov, et al., Abstracts of the Symposium on Modern Problems in Nanocatalysis [in Russian], Uzhgorod, Ukraine, September 24–28, 2012, pp. 43–44.

  5. B. F. Dodge, Chemical Engineering Thermodynamics, McGraw-Hill, New York-London (1944).

    Google Scholar 

  6. K. I. Patrilyak, Zh. Fiz. Khim., 57, No. 12, 2918–2921 (1983).

    CAS  Google Scholar 

  7. K. I. Patrilyak, Inclusion Compounds and Some Problems in Heterogeneous Equilibria [in Russian], Naukova Dumka, Kiev (1987).

    Google Scholar 

  8. K. I. Patrilyak and V. G. Motornyi, Zh. Fiz. Khim., 49, No. 5, 1104–1107 (1975).

    CAS  Google Scholar 

  9. K. I. Patrilyak, Visn. Akad. Nauk URSR, 37, No. 1, 29–36 (1973).

    Google Scholar 

  10. K. I. Zamaraev, Usp. Khim., 62, No. 11, 1051–1063 (1993).

    Article  CAS  Google Scholar 

  11. A. V. Gural’skii, Catalytic Properties of Copper-Cerium-Zirconium Oxide Systems in the Selective Oxidation of Carbon Monoxide Impurities in Hydrogen Media [in Ukrainian], Author’s Abstract of Dissertation in competition for the academic degree of Candidate of the Chemical Sciences, Kyiv (2012).

Download references

Author information

Authors and Affiliations

  1. Institute of Bioorganic Chemistry and Petroleum Chemistry, National Academy of Sciences of Ukraine, Vul. Murmans’ka, 1, Kyiv, 02660, Ukraine

    K. I. Patrylak, L. K. Patrylak & S. V. Konovalov

Authors
  1. K. I. Patrylak
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. L. K. Patrylak
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. S. V. Konovalov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to K. I. Patrylak.

Additional information

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 49, No. 1, pp. 32–36, January-February, 2013.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Patrylak, K.I., Patrylak, L.K. & Konovalov, S.V. Thermodynamic approach to prediction of the effect of size on nanostructure properties. Theor Exp Chem 49, 35–39 (2013). https://doi.org/10.1007/s11237-013-9291-0

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11237-013-9291-0

Keywords

Search

Navigation