Skip to main content
SpringerLink
Log in

Effect of the method of production of TiO2/CdS nanohetero film structures on the effectiveness of photoinduced charge separation

  • Published:
Theoretical and Experimental Chemistry Aims and scope

The properties of TiO2/CdS nanohetero structures produced by the chemical and photocatalytic deposition of CdS nanoparticles on the surface of nanocrystalline films of TiO2 under the conditions of laser pulse photolysis were studied. It was shown that in the case of photocatalytically formed TiO2/CdS nanocomposites the spatial separation of the photogenerated charges between the components of the hetero structure, leading to the formation of intermediates of the photochemical transformations (TiIII centers in the TiO2 nanoparticles and S– radical-anions in the CdS nanoparticles), is an order of magnitude more effective.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. L. Stroyuk, V. V. Shvalagin, A. E. Raevskaya, et. al., Teor. Éksp. Khim., 44, No. 4, 199-220 (2008). [Theor. Experim. Chem., 44, No. 4, 205-231 (2008).]

    Google Scholar 

  2. M. A. Zhukowskiy, A. L. Stroyuk, V. V. Shvalagin, et al., J. Photochem. Photobiol. A. (2009), in the press.

  3. M. Maliarik, V. F. Plyusnin, V. P. Grivin, et al., J. Phys. Chem. A, 112, No. 26, 5786-5793 (2008).

    Article  CAS  Google Scholar 

  4. D. Bahnemann, A. Henglein, J. Lilie, L. Spanhel, J. Phys. Chem., 88, No. 4, 709-711 (1984).

    Article  CAS  Google Scholar 

  5. N. Serpone, D. Lawless, R. Khairutdinov, E. Pelizzetti, J. Phys. Chem., 99, No. 45, 16655-16661 (1995).

    Article  CAS  Google Scholar 

  6. Wey Yang Teoh, L. Mädler, D. Beydoun, et al., Chem. Eng. Sci., 60, 5852-5861 (2005).

    Article  Google Scholar 

  7. D. Duonghong, J. Ramsden, and M. Gratzel, J. Am. Chem. Soc., 104, 2977-2985 (1982).

    Article  Google Scholar 

  8. Y. Bessekhouad, N. Chaoui, M. Trzpit, et al., J. Photochem. Photobiol. A, 183, 218-224 (2006).

    Article  CAS  Google Scholar 

  9. Y. Liu, X. Wang, F. Yang, et al., Micropor. Mesopor. Mater., 114, 431-439 (2008).

    Article  CAS  Google Scholar 

  10. P. V. Kamat, N. M. Dimitrijeviæ, R. W. Fessenden, J. Phys. Chem., 91, No. 2, 396-401 (1987).

    Article  CAS  Google Scholar 

  11. T. Rajh, O. I. Micic, D. Lawless, N. Serpone, J. Phys. Chem., 96, No. 11, 4633-4641 (1992).

    Article  CAS  Google Scholar 

  12. C. Liu, A. J. Bard, J. Phys. Chem., 93, 3232-3237 (1989).

    Article  CAS  Google Scholar 

  13. D. V. Bavykin, E. N. Savinov, V. N. Parmon, J. Photochem. Photobiol. A., 130, 57-61 (2000).

    Article  CAS  Google Scholar 

  14. A. L. Stroyuk, V. N. Dzhagan, S. Ya. Kuchmii, et al., Teor. Éksp. Khim., 43, No. 5, 275-281 (2007). [Theor. Experim. Chem., 43, No. 5, 297-305 (2007).]

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. L. V. Pisarzhevskii Institute of Physical Chemistry, National Academy of Sciences of Ukraine, Prospekt Nauky, 31, Kyiv, 03028, Ukraine

    A. L. Stroyuk & S. Ya. Kuchmii

  2. O. O. Chuiko Institute of Surface Chemistry, National Academy of Sciences of Ukraine, Vul. Generala Naumova, 17, Kyiv, 03164, Ukraine

    M. A. Zhukovskii & N. P. Smirnova

  3. Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Ul. Institutskaya, 3, Novosibirsk, 630090, Russian Federation

    E. M. Glebov, V. P. Grivin & V. F. Plyusnin

Authors
  1. A. L. Stroyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. Ya. Kuchmii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. A. Zhukovskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. P. Smirnova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. M. Glebov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. V. P. Grivin
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. V. F. Plyusnin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. L. Stroyuk.

Additional information

Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 45, No. 5, pp. 289-294, September-October, 2009.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Stroyuk, A.L., Kuchmii, S.Y., Zhukovskii, M.A. et al. Effect of the method of production of TiO2/CdS nanohetero film structures on the effectiveness of photoinduced charge separation. Theor Exp Chem 45, 302–307 (2009). https://doi.org/10.1007/s11237-009-9097-2

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11237-009-9097-2

Key words

Search

Navigation