We have used IR spectroscopy to study adsorption of NO, propane, and their mixture on Fe-ZSM-5 in the temperature range 20-350 °C. We show that it is possible to form adsorbed nitrate ions, C-, N-, and O-containing intermediates leading to formation of partial oxidation products: oxygenates and nitrogen-containing compounds.
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 45, No. 2, pp. 121-124, March-April, 2009.
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Alekseenko, L.M., Tel’biz, G.M. & Orlik, S.N. IR spectroscopic signs of surface intermediates of partial oxidation of propane by nitrogen monoxide on Fe-ZSM-5. Theor Exp Chem 45, 131–135 (2009). https://doi.org/10.1007/s11237-009-9075-8
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DOI: https://doi.org/10.1007/s11237-009-9075-8