Based on electronic diffuse reflectance spectra of indicators adsorbed on La2O3–ZrO2, obtained at 25-200 °C, we have shown that the strength of its basic sites sharply increases from H–S ≤ +17.2 to H–S ≤ +33.0 in the range 25-140 °C.
Similar content being viewed by others
References
K. Tanabe, Catalysts and Catalytic Processes [in Russian], Mir, Moscow (1993).
V. V. Brei, D. V. Shistka, and G. M. Telbiz, Pol. J. Chem., 82, Nos. 1/2, 179-182 (2008).
J. F. Haw, X. T. Nicolas, L. W. Beck, and D. B. Ferguson, Accts. Chem. Res., 95, No. 3, 259-267 (1996).
V. V. Brei, Teor. Éksp. Khim., 44, No. 5, 310-314 (2008). [Theor. Experim. Chem., 44, No. 5, 320-324 (2008).]
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 45, No. 2, pp. 112-114, March-April, 2009.
Rights and permissions
About this article
Cite this article
Brei, V.V., Shistka, D.V. & Levitskaya, S.I. Variation in the strength of base sites in the system La2O3–ZrO2 in the range 25-200°C. Theor Exp Chem 45, 122–124 (2009). https://doi.org/10.1007/s11237-009-9073-x
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11237-009-9073-x