The characteristics of the sorption of hydrogen by metal–organic framework compounds (MOF) were examined, and the structural and thermodynamic factors that favor the sorption of H2 by such substances were determined. The effect of the structure of the MOF and the size and geometry of the pores on the sorption characteristics was analyzed.
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 45, No. 2, pp. 67-87, March-April, 2009.
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Kolotilov, S.V., Pavlishchuk, V.V. Effect of structural and thermodynamic factors on the sorption of hydrogen by metal–organic framework compounds. Theor Exp Chem 45, 75–97 (2009). https://doi.org/10.1007/s11237-009-9068-7
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DOI: https://doi.org/10.1007/s11237-009-9068-7