Abstract
For semi-interpenetrating polymer networks (semi-IPNs) based on an incompatible polyurethane network/linear polymethylmethacrylate pair formed in situ in the presence of 3d metal chelates, we have studied the effect of the system composition on the kinetics of formation of the components and the nature of complex formation between the metal compound and the polymer matrix. The ratio of the system components has been shown to have an effect on the selection of the macroligand in formation of complexes of the metal chelate with the polar groups of the semi-IPN, where the general character of the kinetic behavior for the formation of the network and the linear polymer is preserved.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Yu. S. Lipatov, Phase-Separated Interpenetrating Polymer Networks, UsChTU, Dnepropetrovsk (2001).
J. Kim, J. Kwar, and D. Kim, Polym. Adv. Technol., 14, No. 1, 58–65 (2003).
I. Aravind, P. Albert, C. Ranganathaiah, et al., Polymer, 45, 4925–4937 (2004).
J.-V. Huang, J. Appl. Polym. Sci., 88, No. 9, 2247–2252 (2003).
T. T. Alekseeva, U. S. Lipatov, N. V. Babkina, et al., Polymer, 46, 319–428 (2005).
N. V. Kozak, Yu. N. Nizel’skii, L. F. Kosyanchuk, et al., Teor. Éksp. Khim., 46, No. 4, 252–256 (2005).
Yu. N. Nizel’skii, Catalytic Properties of Metal β-Diketonates [in Russian], Nauk. Dumka, Kiev (1983).
A. A. Shklyaev and V. F. Anufrienko, Zh. Strukt. Khim., 16, No. 36, 1082–1095 (1975).
N. V. Kozak, L. F. Kosyanchuk, Yu. S. Lipatov, et al., Vysokomolek. Soedin. A, 42, No. 12, 2104–2110 (2000).
Yu. S. Lipatov, L. F. Kosyanchuk, N. V. Kozak, et al., Vysokomolek. Soedin. A, 48, No. 4, 616–623 (2006).
Yu. S. Lipatov, T. T. Alekseeva, and V. F. Rosovitskii, Dokl. Akad. Nauk SSSR, 307, No. 4, 883–887 (1989).
A. M. Vasserman and A. L. Kovarskii, Spin Labels and Probes in the Physical Chemistry of Polymers [in Russian], Nauka, Moscow (1986).
T. É. Lipatova and Yu. N. Nizel’skii, Advances in Polyurethane Chemistry [in Russian], Nauk. Dumka, Kiev (1972).
Yu. S. Lipatov, L. F. Kosyanchuk, N. V. Babkina, et al., Dop. NAN Ukrainy, No. 7, 134–141 (2005).
G. P. Gladyshev and V. A. Popov, Radical Polymerization at High Conversions [in Russian], Moscow (1974).
Author information
Authors and Affiliations
Additional information
__________
Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 42, No. 6, pp. 351–356, November–December, 2006.
Rights and permissions
About this article
Cite this article
Kosyanchuk, L.F., Kozak, N.V., Antonenko, O.I. et al. Kinetics of formation of a linear polymer-polymer network system in the presence of 3d metal chelates. Theor Exp Chem 42, 357–363 (2006). https://doi.org/10.1007/s11237-006-0066-8
Received:
Issue Date:
DOI: https://doi.org/10.1007/s11237-006-0066-8