Abstract
Temperature transitions have been studied in the structure of triblock copolymers based on poly(ethylene oxide) and poly(acrylamide) (PAA-b-PEO-b-PAA) with central blocks of varying length and compared with individual polymers and polymer mixtures with analogous composition. It has been established that interaction of the polymer components on account of the formation of systems of intramolecular hydrogen bonds is strengthened by the presence of covalent bonds between the components.
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References
Riess Gerard, Progr. Polym. Sci., 28, 1107–1170 (2003).
Patrick Lim Soo and Adi Eisenberg, J. Polym. Sci. B, 42, 923–938 (2004).
F. Lin, Y. Frere, and J. Francois, Polymer, 42, 2969–2983 (2001).
Patrick Lim Soo, Laibin Luo, Dusica Maysinger, and Adi Eisenberg, Langmuir, 18, 9996–10004 (2002).
Matthew Moffitt, H. Vali, and Adi Eisenberg, Chem. Mater., 10, 1021–1028 (1998).
E. Alami, M. Almgren, and J. Franceis, Macromolecules, 29, 2229–2243 (1996).
T. M. Birshtein and V. M. Amoskov, Vysokomolek. Soed., 42, No. 12, 2286–2327 (2000).
A. Noshei and J. MacGrad, Block-copolymers [Russian translation], Mir, Moscow (1980).
N. M. Bol’bit and Yu. N. Korneev, Vysokomolek. Soed., A, 34, No. 5, 77–85 (1992).
T. B. Zheltonozhskaya, N. E. Zagdanskaya, O. V. Demchenko, et al., Usp. Khim., 73, No. 8, 877–896 (2004).
K. Pielichowski, K. Flejtuch, and J. Pielichowski, Polymer, 45, 1235–1242 (2004).
Zhao Wenwei, Yu Li, Zhong Xiaognang, et al., J. Macromol. Sci. B, 34, No. 3, 231–237 (1995).
G. Alberg, A. Nielson, and G. Uomi, Theory of Splines and Its Applications [Russian translation], Mir, Moscow (1972).
N. M. Permyakova, T. B. Zheltonozhskaya, O. V. Demchenko, et al., Ukr. Khim. Zh., 68, No. 10, 123–128 (2002).
V. A. Bershtein and V. M. Egorov, Differential Scanning Calorimetry in the Physical Chemistry of Polymers [in Russian], Khimiya, Leningrad (1990).
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 41, No. 6, pp. 364–370, November–December, 2005.
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Permyakova, N.M., Zheltonozhskaya, T.B., Shilov, V.V. et al. Structure of triblock-copolymers based on poly(ethylene oxide) and poly(acrylamide) with central blocks of varying lengths. Theor Exp Chem 41, 382–388 (2005). https://doi.org/10.1007/s11237-006-0007-6
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DOI: https://doi.org/10.1007/s11237-006-0007-6