Abstract
We have observed damped oscillations of increasing frequency in alkylation of benzene by 1-decene, which we interpret based on surface competition between the benzene and the coke being formed according to a mechanism of alternating inversions of the adsorption layer. We propose a scheme for the inversions in terms of chemical potentials of the adsorbed components. The change in the character of the oscillations is connected with a qualitative change in the coke over time.
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 41, No. 1, pp. 40–44, January–February, 2005.
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Patrilyak, L.K., Manza, I.A. & Okhrimenko, M.V. Oscillatory character of deactivation of zeolite catalysts in carbonium ion conversions of hydrocarbons. Theor Exp Chem 41, 42–47 (2005). https://doi.org/10.1007/s11237-005-0020-1
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DOI: https://doi.org/10.1007/s11237-005-0020-1