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Catalytic activity of heterobimetallic M1/M2 complexes (M1=Ni, Cu; M2=Mn, Zn) in the decomposition of hydrogen peroxide

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Abstract

The kinetics of the decomposition of hydrogen peroxide in the presence of heterobimetallic complex compounds [M1(L1/L2)][M2Cl4] (M1=Ni, Cu; M2=Zn, Mn; L1=4,6,6-trimethyl-1,9-diamino-3,7-diaza-3-nonene); L2=1,15-dihydroxy-7,9,9-trimethyl-3,6,10,13-tetraaza-6-pentadecene), obtained by direct template synthesis, were studied. It was shown that the copper compounds have high catalytic activity, whereas the nickel complexes are inactive. A mathematical model is proposed for description of the kinetic relationships, and the main characteristics of the process are obtained.

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Authors and Affiliations

  1. Taras Shevchenko Kyiv National University, 60 Volodymyrs’ka Vul., 01033, Kyiv, Ukraine

    V. E. Diyuk, D. V. Shevchenko, T. N. Bezuglaya, V. N. Kokozei & A. N. Savitskaya

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  1. V. E. Diyuk
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  2. D. V. Shevchenko
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  3. T. N. Bezuglaya
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  4. V. N. Kokozei
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  5. A. N. Savitskaya
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 41, No. 1, pp. 17–23, January–February, 2005.

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Diyuk, V.E., Shevchenko, D.V., Bezuglaya, T.N. et al. Catalytic activity of heterobimetallic M1/M2 complexes (M1=Ni, Cu; M2=Mn, Zn) in the decomposition of hydrogen peroxide. Theor Exp Chem 41, 19–25 (2005). https://doi.org/10.1007/s11237-005-0016-x

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  • DOI: https://doi.org/10.1007/s11237-005-0016-x

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