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Kinetics of diethyl sulfide oxidation by hydrogen peroxide and peroxymonocarbonate in the presence of surfactants

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Theoretical and Experimental Chemistry Aims and scope

Abstract

We have studied the effect of different surfactants on the rate of diethyl sulfide (Et2S) oxidation by hydrogen peroxide and peroxymonocarbonate (HCO -4 ) in aqueous solutions. In all the studied cases, the rate of the reaction between Et2S and H2O2 decreases as the surfactant concentration increases. The reaction of Et2S with HCO -4 is catalyzed by cationic surfactants and inhibited by neutral and anionic surfactants.

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Authors and Affiliations

  1. L. M. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, 70 R. Luxemburg Vul., 83114, Donets’k, Ukraine

    V. L. Lobachev, T. M. Prokop’eva & V. A. Savelova

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  1. V. L. Lobachev
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  2. T. M. Prokop’eva
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  3. V. A. Savelova
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Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 40, No. 6, pp. 368–372, November–December, 2004.

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Lobachev, V.L., Prokop’eva, T.M. & Savelova, V.A. Kinetics of diethyl sulfide oxidation by hydrogen peroxide and peroxymonocarbonate in the presence of surfactants. Theor Exp Chem 40, 383–388 (2004). https://doi.org/10.1007/s11237-005-0004-1

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  • DOI: https://doi.org/10.1007/s11237-005-0004-1

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