Skip to main content
Log in

Determination of concentration regions of existence of ternary azeotropes: 1. Systems showing like deviations from ideal behavior

  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

The regions of possible ternary azeotropes can be determined by analysis of the concentration dependences of activity coefficient complexes at infinite dilution, which reflect the deviations of the phases from the Raoult—Dalton law. The case of like deviations of the binary constituents from this law is considered.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. M.P. Susarev (1963) ArticleTitleCharacteristics of Location of Folds in the Pressure Surface of the Liquid—Vapor Ternary System and Shift of the Folds under Varying Temperature: I Zh. Fiz. Khim. 37 IssueID5 1763–1768

    Google Scholar 

  2. M.P. Susarev (1963) ArticleTitleCharacteristics of Location of Folds in the Pressure Surface of the Liquid—Vapor Ternary System and Shift of the Folds under Varying Temperature: II Zh. Fiz. Khim. 37 IssueID9 1944–1949

    Google Scholar 

  3. M.P. Susarev A.G. Marinichev (1965) ArticleTitleDifferential Equations for the Curves of Constancy of Distribution (x (2) i /x (1) j = const) of a Component of a Ternary System between the Coexisting Solution and Ideal Vapor: I. Trend of the Curves and Location of a Ternary Azeotrope in the Concentration Triangle Zh. Fiz. Khim. 39 IssueID8 1970–1977

    Google Scholar 

  4. M.P. Susarev A.G. Marinichev (1965) ArticleTitleDifferential Equations for the Curves of Constancy of Distribution (x (2) i /x (1) j = const) of a Component of a Ternary System between the Coexisting Solution and Ideal Vapor: II. Shift of the Curves under Varying Temperature Zh. Fiz. Khim. 39 IssueID9 2219–2225

    Google Scholar 

  5. M.P. Susarev L.S. Kudryavtseva E.A. Matushkevich (1964) ArticleTitleConcentration Regions of Location and Temperature Shift of Ternary Azeotropes: I Zh. Fiz. Khim. 38 IssueID11 2672–2677

    Google Scholar 

  6. M.P. Susarev L.S. Kudryavtseva L.S. Kudryavtseva E.A. Matushkevich (1963) ArticleTitleConcentration Regions of Location and Temperature Shift of Ternary Azeotropes: II Zh. Fiz. Khim. 37 IssueID1 47–51

    Google Scholar 

  7. M.P. Susarev A.G. Marinichev (1967) ArticleTitleConcentration Regions of Location of Ternary Azeotropes Zh. Fiz. Khim. 41 IssueID7 1800–1802

    Google Scholar 

  8. M.P. Susarev L.S. Kudryavtseva O.G. Eizen (1973) Troinye azeotropnye sistemy Valgus Tallinn

    Google Scholar 

  9. M.P. Susarev A.M. Toikka (1974) ArticleTitleCompositions and Temperature Shifts of Ternary Azeotropes: XII. Azeotrope Parameters Allowed by Stability Conditions Zh. Fiz. Khim. 48 IssueID11 2680–2683

    Google Scholar 

  10. A.V. Storonkin A.G. Morachevskii L.S. Kudryavtseva (1957) ArticleTitleEffect of Temperature and Pressure on the Composition of Ternary Azeotropes Zh. Fiz. Khim. 31 IssueID2 395–402

    Google Scholar 

  11. L.A. Serafimov V.M. Raeva (2003) ArticleTitleLocation of Binary Azeotropes in the Concentration Simplex Teor. Osn. Khim. Tekhnol. 37 IssueID3 272–277

    Google Scholar 

  12. V.M. Raeva A.K. Frolkova L.A. Serafimov (1996) ArticleTitleEvolution of the Composition of Binary Azeotropes Under Variable External Conditions Teor. Osn. Khim. Tekhnol. 30 IssueID1 27–33

    Google Scholar 

  13. G.V. Shutova T.M. Kushner L.A. Serafimov (1992) Evolution of Diagrams of Vapor—Liquid Equilibrium of Biazeotropic Binary Systems under Varying Pressure V.B. Fillipov (Eds) Voprosy termodinamiki geterogennykh sistem i teorii poverkhnostnykh yavlenii S.-Peterb. Gos. Univ. St. Petersburg 64

    Google Scholar 

  14. A.V. Nikitskii T.M. Kushner L.A. Serafimov (1998) ArticleTitleDiagrams of Excess Gibbs Thermodynamic Potential in Ternary Systems Zh. Fiz. Khim. 72 IssueID12 2138–2143

    Google Scholar 

  15. L.A. Serafimov (2001) ArticleTitleClassification of the Phase Diagrams of Real Batch Distillation Teor. Osn. Khim. Tekhnol. 35 IssueID3 252–256

    Google Scholar 

  16. L.A. Serafimov A.K. Frolkova V.M. Raeva (2003) ArticleTitleThermodynamic Analysis of the Wilson Model Using Partial Excess Functions Teor. Osn. Khim. Tekhnol. 37 IssueID2 174–183

    Google Scholar 

  17. L.A. Serafimov (1971) ArticleTitleAzeotropic Relationship and Classification of Multicomponent Mixtures: VIII. General Laws of Tangential Azeotropy Zh. Fiz. Khim. 45 IssueID4 1140–1147

    Google Scholar 

  18. L.A. Serafimov (1971) ArticleTitleAzeotropic Relationship and Classification of Multicomponent Mixtures: IX. Tangential Azeotropy and General Relationship between Singular Points of Different Types Zh. Fiz. Khim. 45 IssueID6 1473–1476

    Google Scholar 

  19. V.T. Zharov L.A. Serafimov (1975) Fizikokhimicheskie osnovy distillyatsii i rektifikatsii Khimiya Leningrad

    Google Scholar 

  20. L.A. Serafimov (1971) ArticleTitleAzeotropic Relationship and Classification of Multicomponent Mixtures: XI. Tangential Azeotropy in Ternary Mixtures and Chains of Topological Structures Zh. Fiz. Khim. 45 IssueID10 2448–2450

    Google Scholar 

  21. Hilmen, E.K., Kiva, V.N., and Skogestad, S., On the Topology of Ternary VLE Diagrams: Elementary Cells, AIChE J. (in press).

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Teoreticheskie Osnovy Khimicheskoi Tekhnologii, Vol. 38, No. 6, 2004, pp. 683–692.

Original Russian Text Copyright © 2004 by Raeva, Serafimov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Raeva, V.M., Serafimov, L.A. Determination of concentration regions of existence of ternary azeotropes: 1. Systems showing like deviations from ideal behavior. Theor Found Chem Eng 38, 644–653 (2004). https://doi.org/10.1007/s11236-005-0039-y

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11236-005-0039-y

Keywords

Navigation