Uniaxial negative thermal expansion in crystals of tienoxolol

Structural Chemistry volume 24, pages279–283(2013)Cite this article

Abstract

The thermal expansion of tienoxolol has been investigated by X-ray powder diffraction up to its melting temperature. The data indicate that the expansion is anisotropic and even negative in one direction of the unit cell. The supramolecular structure formed by hydrogen-bonds reflects that of a trellis, which explains the observed behavior of tienoxolol crystals.

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Acknowledgments

RC thank the Generalitat de Catalunya (2007PIV00011) for an invited position at the Universitat Politècnica de Catalunya. Part of this study was supported by MICINN (grant FIS2011-24439).

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Affiliations

  1. Laboratoire de Chimie Physique, EAD Physico-chimie Industrielle du Médicament (EA4066), Faculté de Pharmacie, Université Paris Descartes, 4, Avenue de l’Observatoire, 75006, Paris, France

    Béatrice Nicolaï, Ivo B. Rietveld, Nathalie Mahé & René Céolin

  2. Grup de Caracterització de Materials (GCM), Departament de Física i Enginyeria Nuclear, Universitat Politècnica de Catalunya, ETSEIB, Diagonal 647, 08028, Barcelona, Spain

    Maria Barrio & Josep-Lluís Tamarit

  3. Solvay SA, 25 rue de Clichy, 75009, Paris, France

    Christophe Guéchot

  4. 78170, La Celle Saint Cloud, France

    Jean-Marie Teulon

Authors
  1. Béatrice Nicolaï
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  2. Ivo B. Rietveld
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  3. Maria Barrio
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  4. Nathalie Mahé
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  5. Josep-Lluís Tamarit
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  6. René Céolin
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  7. Christophe Guéchot
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  8. Jean-Marie Teulon
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Correspondence to Béatrice Nicolaï.

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Nicolaï, B., Rietveld, I.B., Barrio, M. et al. Uniaxial negative thermal expansion in crystals of tienoxolol. Struct Chem 24, 279–283 (2013). https://doi.org/10.1007/s11224-012-0078-z

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Keywords

  • Drug
  • Active pharmaceutical ingredient (API)
  • Crystal structure
  • Solid state