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Uniaxial negative thermal expansion in crystals of tienoxolol

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Abstract

The thermal expansion of tienoxolol has been investigated by X-ray powder diffraction up to its melting temperature. The data indicate that the expansion is anisotropic and even negative in one direction of the unit cell. The supramolecular structure formed by hydrogen-bonds reflects that of a trellis, which explains the observed behavior of tienoxolol crystals.

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Acknowledgments

RC thank the Generalitat de Catalunya (2007PIV00011) for an invited position at the Universitat Politècnica de Catalunya. Part of this study was supported by MICINN (grant FIS2011-24439).

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Correspondence to Béatrice Nicolaï.

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Nicolaï, B., Rietveld, I.B., Barrio, M. et al. Uniaxial negative thermal expansion in crystals of tienoxolol. Struct Chem 24, 279–283 (2013). https://doi.org/10.1007/s11224-012-0078-z

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  • DOI: https://doi.org/10.1007/s11224-012-0078-z

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