Skip to main content
SpringerLink
Log in

Patterns and estimation of the entropies of formation of fluorine containing aqueous anions

  • Brief Communication
  • Published:
Structural Chemistry Aims and scope Submit manuscript

Abstract

Entropies of formation (\(T\Delta_{f}S^{0})\) of aqueous fluorine containing anions were shown to follow different entropic patterns than those of oxygen or hydrogen containing anions. Approaches to estimation of the entropies of formation of these anions are based on “simple” entropic patterns, where simple means the use of parameters derived only from the stoichiometry of these species, which are investigated, discussed and commented upon.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1

References

  1. Ponikvar M, Liebman JF (2006) Struct Chem 17:623

    Article  CAS  Google Scholar 

  2. Ponikvar M, Liebman JF, Struct Chem (2007) DOI:10.1007/s11224-007-9160-3

  3. Jenkins HDB, Pritchett MSF (1983) J Chem Soc Chem Comm 18:1041

    Article  Google Scholar 

  4. Jenkins HDB, Pritchett MSF (1984) J Chem Soc Faraday Trans 80:721

    Article  CAS  Google Scholar 

  5. Jenkins HDB, Morris DFC (1976) Mol Phys 32:231

    Article  CAS  Google Scholar 

  6. Jenkins HDB, Morris DFC (1977) Mol Phys 33:663

    Article  CAS  Google Scholar 

  7. Jenkins HDB, Morris DFC (1977) Phil Mag 35:1091

    Article  CAS  Google Scholar 

  8. Jenkins HDB, Morris DFC (1984) J Chem Soc Faraday Trans 2 80:1167

    Google Scholar 

  9. Jenkins HDB (1993) J Soln Chem 22:1029

    Article  Google Scholar 

  10. Jenkins HDB (1993) J Phys Chem 97:7876

    Article  CAS  Google Scholar 

  11. Jenkins HDB, Marcus Y (1995) Chem Rev 95:2695

    Article  CAS  Google Scholar 

  12. Jenkins HDB, Glasser L (2003) Inorg Chem 42:8702

    Article  CAS  Google Scholar 

  13. Glasser L, Jenkins HDB (2004) Thermochim Acta 414:125

    Article  CAS  Google Scholar 

  14. Mallouk TE (1983) Doctoral Thesis: University of California, Berkeley, Chapter IV

  15. Bartlett N, Yeh S, Kourtakis K, Mallouk TE (1984) J Fluorine Chem 26:97

    Article  CAS  Google Scholar 

  16. Wagman DD, Evans WH, Parker VB, Schumm RH, Halow I, Bailey SM, Churney KL, Nuttall RL (1982) The NBS tables of chemical thermodynamic properties: selected values for inorganic and C1 and C2 organic substances in SI units. J Phys Chem Ref Data 11(Supplement 2)

  17. Larson JW, Su BL (1994) J Chem Eng Data 39:36

    Article  CAS  Google Scholar 

  18. Larson JW (1991) Polyhedron 10:1695

    Article  CAS  Google Scholar 

  19. Devina OA, Kuyunko NS, Efimov ME, Medvedev VA, Khodakovskii IL, Geokhimiya (1983) 8:1150 . See also, Archer, DG (2005) J Chem Eng Data 50: 692.

  20. . Latimer WM, Jolly WL (1953) J Am Chem Soc 75:1548

    Article  CAS  Google Scholar 

  21. Tagirov B, Schott J, Harrichoury JC (2002) Chem Geol 184:301

    Article  CAS  Google Scholar 

  22. Vasil’ev VP, Kozlovskii EV (1974) Zh Neorg Khim 19:1481

    CAS  Google Scholar 

  23. Ahrland S, Kullberg L (1971) Acta Chem Scand 25:3471

    Article  CAS  Google Scholar 

  24. Vasil’ev VP, Kozlovskii EV, Kokurina GL (1977) Zh Neorg Khim 22:1526

    CAS  Google Scholar 

  25. Mesmer RE, Baes CF Jr (1969) Inorg Chem 8:618

    Article  CAS  Google Scholar 

  26. Miller JC, Miller JN (2002) Statistics and chemometrics for analytical chemistry 4th edn. Prentice Hall, Harlow, pp 141–145, 230–231

  27. Some reviews include (a) Barthel-Rosa LP, Gladysz JA (1999) Coord Chem Rev 190–192:587, (b) Gladysz, JA, Curran, DP Editors (2002). Fluorous Chemistry: Tetrahedron Symposium-in-Print Number 91. [In:Tetrahedron, 2002; 58(20)], (c) Zhang W, Curran, DP (2006) Tetrahedron 62:11837, Reichardt C (2007) Org. Proc. Res. Dev 11:105

  28. Archer DG (2005) J Chem Eng Data 50:692

    Article  CAS  Google Scholar 

  29. Jenkins HDB, Glasser L, Klapötke TM, Crawford M-J, Bhasin KK, Lee J, Schrobilgen GJ, Sunderlin LS, Liebman JF (2004) Inorg Chem 43:6238

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Jožef Stefan Institute, Jamova 39, 1000, Ljubljana, Slovenia

    Maja Ponikvar

  2. University of Warwick, Coventry, CV4 7AL, West Midlands, UK

    H. Donald B. Jenkins

  3. Department of Chemistry and Biochemistry, University of Maryland, Baltimore County, Baltimore, MD, 21250, USA

    Joel F. Liebman

Authors
  1. Maja Ponikvar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Donald B. Jenkins
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Joel F. Liebman
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Joel F. Liebman.

Additional information

This article is dedicated to Professor Neil Bartlett, fellow fluorinophile and friend, on the occasion of his 75th birthday.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ponikvar, M., Jenkins, H.D.B. & Liebman, J.F. Patterns and estimation of the entropies of formation of fluorine containing aqueous anions. Struct Chem 18, 883–889 (2007). https://doi.org/10.1007/s11224-007-9189-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11224-007-9189-3

Keywords

Search

Navigation