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One Novel Cu(II)–Amino Acid Schiff Base Complex Derived from Salicylaldehyde and L-Serine: Identification of Unusual Monodentate 4,4′-Bipyridine

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Abstract

One novel copper(II) complex [Cu(L)(4,4′-bipy)](ClO4) (1), (where L: tridentate Schiff base derived from salicylaldehyde and L-serine) has been synthesised and characterised by spectroscopic and electrochemical studies. The single-crystal structure of the complex was determined. The crystal structure features the presence of [Cu(L)(4,4′-bipy)]+ cations and ClO4− anions aggregated by hydrogen bonding. Here, 4,4′-bipyridine functions as a monodentate ligand, which appears to be an unusual phenomenon.

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Authors and Affiliations

  1. Department of Chemistry, Jadavpur University, Kolkata, 700 032, India

    Ruma Karmakar, Chirantan Roy Choudhury & Samiran Mitra

  2. Institut für Anorganische Chemie, Friederich-Alexander-Universität Erlangen-Nürnberg, Egerlandstraße 1, Erlangen, Germany, D-91058

    Lutz Dahlenburg

Authors
  1. Ruma Karmakar
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  2. Chirantan Roy Choudhury
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  3. Samiran Mitra
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  4. Lutz Dahlenburg
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Correspondence to Samiran Mitra.

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Karmakar, R., Choudhury, C.R., Mitra, S. et al. One Novel Cu(II)–Amino Acid Schiff Base Complex Derived from Salicylaldehyde and L-Serine: Identification of Unusual Monodentate 4,4′-Bipyridine. Struct Chem 16, 611–616 (2005). https://doi.org/10.1007/s11224-005-7573-4

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  • DOI: https://doi.org/10.1007/s11224-005-7573-4

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