The study of the absolute line intensities in the high-resolution spectrum of the D234S molecule in the range of 2300–2900 cm–1 has been carried out for the first time. As a result of our analysis, about 800 experimental intensities of vibrational-rotational transitions have been obtained for the v1 + v2 and v2 + v3 bands, and a set of 6 parameters of the effective dipole moment has been calculated, which reproduce the initial experimental line intensities with standard deviation drms = 9.7%. A list of transitions with frequencies and line intensities in the range under study has been compiled.
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 170–177, January, 2022.
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Belova, A.S., Bekhtereva, E.S., Ersin, T. et al. Experimental Ro-Vibrational Line Intensities for the v1 + v2 and v2 + v3 Bands of the D234S Molecule. Russ Phys J 65, 185–192 (2022). https://doi.org/10.1007/s11182-022-02621-5
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DOI: https://doi.org/10.1007/s11182-022-02621-5