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Effect of a Homogeneous Dielectric Medium on the Luminescence of Singlet Oxygen

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Russian Physics Journal Aims and scope

Results of an analysis of our and literature data devoted to the study of the effect of a homogeneous dielectric medium on the rate constant of the \( {}^1{\Delta}_g{\to}^3{\Sigma}_g^{-} \) radiative transition in singlet oxygen are presented. It is shown that the influence of the refractive index n on the radiative rate constant is due to the change of the density of photon states and the local field factor. At the same time, in a dielectric medium, the transition dipole moment increases significantly as a result of contact of singlet oxygen with solvent molecules. Only taking into account all of the above factors will provide a consistent explanation of the influence of the medium on the rate constant of the luminescence of singlet oxygen.

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Authors and Affiliations

  1. B. I. Stepanov Institute of Physics, National Academy of Sciences of Belarus, Minsk, Belarus

    B. M. Dzhagarov, E. S. Zharnikova & M. V. Parkhats

  2. University of Waterloo, Waterloo, Canada

    V. A. Galievsky

  3. York University, Toronto, Canada

    A. S. Stasheuski

Authors
  1. B. M. Dzhagarov
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  2. E. S. Zharnikova
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  3. V. A. Galievsky
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  4. A. S. Stasheuski
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  5. M. V. Parkhats
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Correspondence to B. M. Dzhagarov.

Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 22–29, November, 2021.

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Dzhagarov, B.M., Zharnikova, E.S., Galievsky, V.A. et al. Effect of a Homogeneous Dielectric Medium on the Luminescence of Singlet Oxygen. Russ Phys J 64, 2008–2016 (2022). https://doi.org/10.1007/s11182-022-02550-3

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  • DOI: https://doi.org/10.1007/s11182-022-02550-3

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