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Reaction Rates in a Deformable Solid in Terms of the Thermodynamics of Irreversible Processes

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Russian Physics Journal Aims and scope

Based on the thermodynamics of irreversible processes, the relationship between the reaction rate in a deformable solid and the stresses is demonstrated without introducing any additional hypotheses. Well known procedures of accounting for the dependence of the reaction rate on the structure are described. A possible generalization of the classical models by extending the thermodynamics is presented. An example of a transition from the continuum modeling to a two-level modeling is given, which makes it possible to establish a relationship between the parameters affecting the reaction rate at different scale levels. A similar approach can be applied to any scalar process.

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Authors and Affiliations

  1. Institute of Strength Physics and Materials Science of the Siberian Branch of the Russian Academy of Sciences, Tomsk, Russia

    A. G. Knyazeva

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  1. A. G. Knyazeva
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Correspondence to A. G. Knyazeva.

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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 111–116, October, 2021.

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Knyazeva, A.G. Reaction Rates in a Deformable Solid in Terms of the Thermodynamics of Irreversible Processes. Russ Phys J 64, 1907–1914 (2022). https://doi.org/10.1007/s11182-022-02540-5

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  • DOI: https://doi.org/10.1007/s11182-022-02540-5

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