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Dipole Moment Operator and Spectral Parameters of Torsion Transitions

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Russian Physics Journal Aims and scope

Analytical expressions for matrix elements of the dipole moment operator for internal rotation are obtained. Quantitative measures for spectroscopic parameters of transitions associated with specific potential wells on the potential energy surface (conformers) are proposed. The relations obtained are illustrated by numerical examples and diagrams.

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Authors and Affiliations

  1. Tver Medical University, Tver, Russia

    V. V. Turovtsev

  2. Tver State University, Tver, Russia

    V. V. Turovtsev, A. N. Belov, M. Yu. Orlov & E. M. Chernova

Authors
  1. V. V. Turovtsev
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  2. A. N. Belov
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  3. M. Yu. Orlov
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  4. E. M. Chernova
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Corresponding author

Correspondence to V. V. Turovtsev.

Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 157–162, August, 2021.

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Turovtsev, V.V., Belov, A.N., Orlov, M.Y. et al. Dipole Moment Operator and Spectral Parameters of Torsion Transitions. Russ Phys J 64, 1553–1559 (2021). https://doi.org/10.1007/s11182-021-02489-x

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  • DOI: https://doi.org/10.1007/s11182-021-02489-x

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