The scattering cross sections of rotational excitations of O3 by collisions with noble gas atoms (Ar and He) have been calculated using the two-body scheme implemented in the MOLSCAT2020 package. All O3 energy levels up to Jmax = Kmax = 5 and Jmax = Kmax = 7 that correspond to 18 and 32 coupled channel equations have been included. Dependences of the scattering cross sections on the collision energy are analyzed, and the most probable excited O3 rotational states are determined. The rate coefficients are calculated at temperatures of 5–300 K. The construction of the radial part of the angular coefficients of the interaction potential is also discussed.
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 162–170, July, 2021.
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Egorov, O.V., Tretyakov, A.K. Excitation and Quencing of Rotational Energy Levels of the О3 Ozone Molecule by Collisions with Noble Gas Atoms (Ar and He). Russ Phys J 64, 1363–1372 (2021). https://doi.org/10.1007/s11182-021-02462-8
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DOI: https://doi.org/10.1007/s11182-021-02462-8