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Effect of Boron on the Combustion Parameters of Hem and Oxidation of Al/B and Ti/B Nanopowders

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The paper presents the thermodynamic calculation results of the effect of boron content on the combustion parameters of high-energy materials (HEMs) based on ammonium perchlorate, butadiene rubber, and aluminum and titanium powders as well as the thermal analysis data for the Al and Ti nanopowders and the Al/В and Ti/B mechanical mixtures. The dependences of the combustion temperature, specific impulse, and mass concentration of condensed HEM combustion products on the metal/boron component ratio are obtained. It is found that with an increase of boron concentration in the Al-containing HEM, the combustion temperature and specific impulse decrease by 16% and 3.3%, respectively. Whereas for the Ti-containing HEM, the specific impulse increases by 7.7% for a component ratio Ti/B = 20/80. The thermal analysis of metal nanopowders in the air showed that the maximum oxidation rates of Al/В and Ti/B increase with the increase of the boron content in the mechanical mixture.

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Authors and Affiliations

  1. National Research Tomsk Polytechnic University, Tomsk, Russia

    A. G. Korotkikh & I. V. Sorokin

Authors
  1. A. G. Korotkikh
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  2. I. V. Sorokin
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Correspondence to A. G. Korotkikh.

Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 3–8, April, 2021.

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Korotkikh, A.G., Sorokin, I.V. Effect of Boron on the Combustion Parameters of Hem and Oxidation of Al/B and Ti/B Nanopowders. Russ Phys J 64, 567–573 (2021). https://doi.org/10.1007/s11182-021-02387-2

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  • DOI: https://doi.org/10.1007/s11182-021-02387-2

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