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Determining the Parameters of the Effective Rovibrational Hamiltonian of the ν7+ν8 Band of the Ethylene-1-13C Molecule

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The spectrum of the ν7 + ν8 band of the ethylene-1-13C (13C12СH4) molecule is recorded with a Bruker IFS 125 HR Fourier spectrometer in the range from 1500 to 2100 cm–1 with a resolution of 0.0025 cm–1. As a result of analysis of the experimental spectrum, more than 1000 transitions belonging to the ν7 + ν8 band are assigned. Parameters of the Hamiltonian obtained as a result of solving the inverse spectroscopic problem reproduce 400 initial experimental energies with error close to the experimental one.

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References

  1. O. N. Ulenikov, G. A. Onopenko, N. E. Tyabaeva, et al., J. Mol. Spectrosc., 193, 249–259 (1999).

    Article  ADS  Google Scholar 

  2. O. N. Ulenikov, G. A. Onopenko, N. E. Tyabaeva, et al., J. Mol. Spectrosc., 186, 293–313 (1997).

    Article  ADS  Google Scholar 

  3. J.-J. Zheng, O. N. Ulenikov, G. A. Onopenko, et al., Mol. Phys., 99, 931–937 (2001).

    Article  ADS  Google Scholar 

  4. O. N. Ulenikov, E. S. Bekhtereva, Y. V. Krivchikova, et al., J. Quant. Spectrosc. Radiat. Transfer, 166, 13–22 (2015).

    Article  ADS  Google Scholar 

  5. O. N. Ulenikov, E. S. Bekhtereva, G. A. Onopenko, et al., J. Mol. Spectrosc., 208, 236–248 (2001).

    Article  ADS  Google Scholar 

  6. O. N. Ulenikov, O. V. Gromova, Y. S. Aslapovskaya, et al., J. Quant. Spectrosc. Radiat. Transfer, 118, 14–25 (2013).

    Article  ADS  Google Scholar 

  7. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, et al., J. Quant. Spectrosc. Radiat. Transfer, 149, 318–333 (2014).

    Article  ADS  Google Scholar 

  8. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, et al., J. Quant. Spectrosc. Radiat. Transfer, 151, 224–238 (2015).

    Article  ADS  Google Scholar 

  9. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, et al., J. Mol. Spectrosc., 317, 32–40 (2015).

    Article  ADS  Google Scholar 

  10. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, et al., J. Quant. Spectrosc. Radiat. Transfer, 161, 180–196 (2015).

    Article  ADS  Google Scholar 

  11. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, et al., J. Mol. Spectrosc., 313, 4–13 (2015).

    Article  ADS  Google Scholar 

  12. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, et al., Quant. Spectrosc. Radiat. Transfer, 164, 117–128 (2015).

    Article  ADS  Google Scholar 

  13. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, et al., J. Quant. Spectrosc. Radiat. Transfer, 187, 403–413 (2017).

    Article  ADS  Google Scholar 

  14. Yu. S. Aslapovskaya, O. V. Gromova, K. B. Berezkin, et al., Russ. Phys. J., 60, No. 2, 273–278 (2017).

    Article  Google Scholar 

  15. I. A. Konov, Yu. V. Chertavskikh, A. L. Fomchenko, et al., Russ. Phys. J., 58, No. 11, 1587–1591 (2015).

    Article  Google Scholar 

  16. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, et al., J. Quant. Spectrosc. Radiat. Transfer, 170, 69–82 (2016).

    Article  ADS  Google Scholar 

  17. O. N. Ulenikov, A. B. Malikova, M. Koivusaari, et al., J. Mol. Spectrosc., 176, 229–235 (1996).

    Article  ADS  Google Scholar 

  18. O. N. Ulenikov, A.-W. Liu, E. S. Bekhtereva, et al., J. Mol. Spectrosc., 234, 270–278 (2005).

    Article  ADS  Google Scholar 

  19. O. N. Ulenikov, O. V. Gromova, E. S. Bekhtereva, et al., J. Quant. Spectrosc. Radiat. Transfer, 112, 486–512 (2011).

    Article  ADS  Google Scholar 

  20. J. K. G. Watson, J. Chem. Phys., 46, 1935–1949 (1967).

    Article  ADS  Google Scholar 

  21. O. N. Ulenikov, A.-W. Liu, E. S. Bekhtereva, et al., J. Mol. Spectrosc., 226, 57–70 (2004).

    Article  ADS  Google Scholar 

  22. O. N. Ulenikov, A.-W. Liu, E. S. Bekhtereva, et al., J. Mol. Spectrosc., 228, 110–119 (2004).

    Article  ADS  Google Scholar 

  23. O. N. Ulenikov, E. S. Bekhtereva, S. V. Grebneva, et al., J. Mol. Phys., 104, 3371–3386 (2006).

    Article  ADS  Google Scholar 

  24. O. N. Ulenikov, E. S. Bekhtereva, V. A. Kozinskaia, et al., J. Mol. Spectrosc., 215, 295–308 (2002).

    Article  ADS  Google Scholar 

  25. S.-M. Hu, O. N. Ulenikov, G. A. Onopenko, et al., J. Mol. Spectrosc., 203, 228–234 (2000).

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Institute of Physics and Technology of the National Research Tomsk Polytechnic University, Tomsk, Russia

    Yu. S. Aslapovskaya

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  1. Yu. S. Aslapovskaya
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Correspondence to Yu. S. Aslapovskaya.

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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 87–90, February, 2018.

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Aslapovskaya, Y.S. Determining the Parameters of the Effective Rovibrational Hamiltonian of the ν7+ν8 Band of the Ethylene-1-13C Molecule. Russ Phys J 61, 299–303 (2018). https://doi.org/10.1007/s11182-018-1401-y

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  • DOI: https://doi.org/10.1007/s11182-018-1401-y

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