On the basis of the assumption of the electron density fluctuation at the band degradation, a calculation parameter (the radius R) of the half-width of the probability distribution over the coordinate R is identified at the level of the maximum electron density fluctuation (at a maximum of the Gaussian function). Based on an analysis of the crystallization process and high polymorphic transformations bcc → fcc, the reasons for the formation of bcc, fcc, hexagonal, and tetragonal structures from the liquid phase, as well as for the high temperature bcc → hcp transition in the solid phase are established using the calculated parameter (the radius R) in the solid and liquid phases.
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 72–76, December, 2015.
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Filippov, E.S. Model of High Temperature Phase Transitions in Metals. Russ Phys J 58, 1747–1752 (2016). https://doi.org/10.1007/s11182-016-0711-1
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DOI: https://doi.org/10.1007/s11182-016-0711-1