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Isotope Substitution Effect in Polyatomic Molecules on the Example of 13C2H4 ← 12C2H4 Substitution

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Russian Physics Journal Aims and scope

General points of the theory of isotope substitution are applied to an analysis of the isotope substitution effect for the substitution 13C2H4←12C2H4 in the ethylene molecule. On the basis of the isotope relations so obtained, numerical predictions of band centers and the most significant rotational, centrifugal, and resonance parameters are made here for the first time for the four lower vibrational states of the 13C2H4 molecule, which can be used to analyze the complicated vibrational-rotational structure of the above-mentioned vibrational states.

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Authors and Affiliations

  1. Institute of Physics and Technology of the National Research Tomsk Polytechnic University, Tomsk, Russia

    E. S. Bekhtereva, O. V. Gromova, K. B. Berezkin & N. V. Kashirina

  2. National Research Tomsk State University, Tomsk, Russia

    E. S. Bekhtereva & I. A. Konov

  3. Institute of Theoretical and Physical Chemistry, Braunschweig University of Technology, Braunschweig, Germany

    S. Bauerecker

Authors
  1. E. S. Bekhtereva
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  2. O. V. Gromova
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  3. K. B. Berezkin
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  4. N. V. Kashirina
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  5. I. A. Konov
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  6. S. Bauerecker
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Correspondence to E. S. Bekhtereva.

Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 83–88, November, 2015.

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Bekhtereva, E.S., Gromova, O.V., Berezkin, K.B. et al. Isotope Substitution Effect in Polyatomic Molecules on the Example of 13C2H4 ← 12C2H4 Substitution. Russ Phys J 58, 1573–1580 (2016). https://doi.org/10.1007/s11182-016-0685-z

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  • DOI: https://doi.org/10.1007/s11182-016-0685-z

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