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On the Determination of the Spectroscopic Parameters of Axially Symmetric XYZ 3 (C 3v) Molecules

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Based on the formalism of irreducible tensor operators, the operator matrix of the effective rotational operator is determined in the general form for XYZ 3-type molecules of axial symmetry. Based on the symmetric properties of the Hamiltonian and the vibrational wave functions of molecules of this type, a number of previously unknown relationships are derived for the spectroscopic parameters.

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Authors and Affiliations

  1. National Research Tomsk State University, Tomsk, Russia

    A. L. Fomchenko, A. G. Litvinovskaya, I. B. Bolotova, N. I. Raspopova, Yu. S. Aslapovskaya, V. A. Zamotaeva, Yu. V. Krivchikova & Yu. V. Chertavskikh

Authors
  1. A. L. Fomchenko
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  2. A. G. Litvinovskaya
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  3. I. B. Bolotova
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  4. N. I. Raspopova
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  5. Yu. S. Aslapovskaya
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  6. V. A. Zamotaeva
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  7. Yu. V. Krivchikova
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  8. Yu. V. Chertavskikh
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Corresponding author

Correspondence to A. G. Litvinovskaya.

Additional information

Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 104–109, July, 2013.

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Fomchenko, A.L., Litvinovskaya, A.G., Bolotova, I.B. et al. On the Determination of the Spectroscopic Parameters of Axially Symmetric XYZ 3 (C 3v) Molecules. Russ Phys J 56, 837–844 (2013). https://doi.org/10.1007/s11182-013-0107-4

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  • DOI: https://doi.org/10.1007/s11182-013-0107-4

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