Temperature dependence of the intensity of annihilation slowed-down fluorescence is studied for aromatic molecules in frozen n-paraffin solutions. With increasing temperature, regions with increased slowed-down fluorescence intensity are established for molecules expelled to the surface of small crystals of the solvent in the process of its freezing. It is assumed that this effect is caused by the increasing number of annihilating pairs involved in slowed-down fluorescence emission. The number of annihilating pairs increases due to rotation of pairs of triplet molecules with parallel directions of magnetic moments in the position with antiparallel direction of the magnetic moments.
Similar content being viewed by others
References
S. A. Bagnich, Fiz. Tverd. Tela, 42, No. 10, 1729–1756 (2000).
V. V. Bryukhanov, I. G. Samusev, and S. G. Karstina, Zh. Prikl. Spektrosk., 71, No. 1, 49–53 (2004).
O. I. Kulikova, T. V. Zheludkova, and V. V. Solodunov, Russ. Phys. J., 50, No. 12, 1171–1177 (2007).
D. A. Kolosov, M. I. Deryabin, I. A. Dobrovol’skaya, and I. V. Gadzhialieva, Zh. Prikl. Spektrosk., 78, No. 4, 641–644 (2011).
V. V. Solodunov and D. M. Grebenshchikov, Opt. Spektrosk., 51, No. 2, 374–376 (1981).
D. M. Grebenshchikov and R. I. Personov, Opt. Spektrosk., 26, No. 2, 264–270 (1969).
M. I. Deryabin, O. I. Kulikova, and V. V. Solodunov, Zh. Prikl. Spektrosk., 67, No. 6, 735–737 (2000).
M. I. Deryabin and O. I. Kulikova, Zh. Prikl. Spektrosk., 70, No. 6, 779–783 (2003).
M. I. Deryabin, A. V. Glushkov, and A. Yu. Shal’nev, Russ. Phys. J., 46, No. 7, 641–645 (2003).
J. A. Barltrop and J. D. Coil, Excited States in Organic Chemistry [Russian translation], Mir, Moscow (1978).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 100–103, January, 2012.
Rights and permissions
About this article
Cite this article
Zhdanova, N.V., Deryabin, M.I. & Solodunov, V.V. Temperature dependence of the intensity of slowed-down fluorescence for aromatic compounds in n-paraffin matrices. Russ Phys J 55, 236–239 (2012). https://doi.org/10.1007/s11182-012-9800-y
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11182-012-9800-y