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Dual fluorescence in donor-acceptor molecules and the effect of fluorination

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Abstract

Fluorescent properties of the P4CF2 and P4CF3 molecules are studied by quantum-chemical methods taking into account the interaction with a polar solvent. It is shown that the molecules exhibit two minima of the potential where hydrogen bonding with a proton-donor solvent can occur. A mechanism responsible for two-band anomalous fluorescence in para- and orthoposions is disccussed. The mechanism was earlier described in [2]. The effect of fluorine substitution in para- and orthopositions is also considered. It is found that strong hydrogen bonding takes place to give a molecule — polar solvent complex where two radiative states of different origin can occur.

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REFERENCES

  1. E. Lippert, W. Luder, F. Moll, et al, Angew. Chem., 73, No.21, 695 (1961).

    Google Scholar 

  2. V. Ya. Artyukhov and O.V. Smirnov, Russ. Phys. J., No. 5, 484 (2003).

  3. Z. R. Grabowski, Acta Physica Polonica, A71, No.5, 743 (1985).

    Google Scholar 

  4. W. S. Struve and P. M. Rentzepis, J. Chem. Phys., 60, No.4, 1533 (1974).

    Google Scholar 

  5. A. Weller, Z. Elektrochem., 60, 1144 (1956).

    Google Scholar 

  6. S. I. Druzhinin and K. A. Zachariasse, in: Book of Abstracts XX Int. Conf. Photochemistry, Moscow, 2001.

  7. V. Ya. Artyukhov and A. I. Galeeva, Sov. Phys. J., No. 11, 949 (1986).

  8. V. Ya. Artyukhov, Zh. Strukt. Khim., 19, No.3, 418 (1978).

    Google Scholar 

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Authors and Affiliations

  1. V. D. Kuznetsov Siberian Physical-Technical Institute, Tomsk State University, Tomsk

    V. Ya. Artyukhov & O. V. Smirnov

Authors
  1. V. Ya. Artyukhov
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  2. O. V. Smirnov
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Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 19–22, October, 2004.

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Artyukhov, V.Y., Smirnov, O.V. Dual fluorescence in donor-acceptor molecules and the effect of fluorination. Russ Phys J 47, 983–987 (2004). https://doi.org/10.1007/s11182-005-0011-7

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  • DOI: https://doi.org/10.1007/s11182-005-0011-7

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