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Study of reaction routes in sulfoination of 2-aminothiazoles with chlorosulfonic acid

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Abstract

The sulfonation of 4-substituted 2-aminothiazoles with chlorosulfonic acid under mild conditions afforded primarily 2-amino-5-thiazolesulfonic acids that at heating in sulfuric acid rearranged into the corresponding stable 2-thiazolesulfamoylic acids.

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Authors and Affiliations

  1. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of the Ukraine, 83114, Donetsk, Ukraine

    S. N. Lyashchuk, V. I. Enya, T. F. Doroshenko & Yu. G. Skrypnik

Authors
  1. S. N. Lyashchuk
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  2. V. I. Enya
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  3. T. F. Doroshenko
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  4. Yu. G. Skrypnik
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Additional information

Translated from Zhurnal Organicheskoi Khimii, Vol. 40, No. 11, 2004, pp. 1695–1698.

Original Russian Text Copyright © 2004 by Lyashchuk, Enya, Doroshenko, Skrypnik.

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Lyashchuk, S.N., Enya, V.I., Doroshenko, T.F. et al. Study of reaction routes in sulfoination of 2-aminothiazoles with chlorosulfonic acid. Russ J Org Chem 40, 1647–1650 (2004). https://doi.org/10.1007/s11178-005-0073-6

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  • DOI: https://doi.org/10.1007/s11178-005-0073-6

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