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Kinetics and mechanism of reaction between polyfluorinated alcohols and thionyl chloride

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Abstract

Complexing of polyfluorinated alcohols with triethylamine was studied by means of microcalorimetry, IR and NMR spectroscopy. The reaction kinetics of these polar complexes with thionyl chloride was investigated using calorimetry of heat fluxes applying mathematical simulation procedure. The second order of nucleophilic substitution reaction of chlorine by polyfluoroalkoxy group was established.

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REFERENCES

  1. Rakhimov, A.I. and Vostrikova, O.V., Zh. Org. Khim., 1999, vol. 35, p. 815.

    Google Scholar 

  2. Storojakova, N.A., Jeltobruchov, V., Zauer, E.A., and Rakhimov, A.I., Russian Polymer News, 2000, no. 3; Storozhakova, N.A., Cand. Sci. (Chem.) Dissertation, Volgograd, 1998.

  3. Smith, A. L., Applied Infra-Red Spectroscopy, NewYork: Wiley, 1979.

    Google Scholar 

  4. Pogorelyi, V.K. and Vishnyakova, T.B., Usp. Khim., 1984, p. 1985.

  5. Sigeru, Oae, Khimiya organicheskikh soedinenii sery (Chemistry of Organic Compunds of Sulfur), Moscow: Khimiya, 1975, 11p.

    Google Scholar 

  6. Calvet, E. and Prat, H., Microcalorimetry, New York: Macmillan Publisher, 1963.

    Google Scholar 

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Authors and Affiliations

  1. Volgograd State Technical University, 400131, Volgograd, Russia

    A. I. Rakhimov, Yu. V. Popov, V. M. Volchkov, O. V. Vostrikova & E. A. Zauer

Authors
  1. A. I. Rakhimov
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  2. Yu. V. Popov
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  3. V. M. Volchkov
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  4. O. V. Vostrikova
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  5. E. A. Zauer
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Additional information

Translated from Zhurnal Organicheskoi Khimii, Vol. 40, No. 11, 2004, pp. 1628–1631.

Original Russian Text Copyright © 2004 by Rakhimov, Popov, Vostrikova, Vostrikova, Zauer.

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Rakhimov, A.I., Popov, Y.V., Volchkov, V.M. et al. Kinetics and mechanism of reaction between polyfluorinated alcohols and thionyl chloride. Russ J Org Chem 40, 1579–1582 (2004). https://doi.org/10.1007/s11178-005-0063-8

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  • DOI: https://doi.org/10.1007/s11178-005-0063-8

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