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Tetrazoles: XLVII. A route to tetrazole-containing dendrimers

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Abstract

The reaction of 5-methylsulfonyl-1-phenyltetrazole with pentaerythritol in acetonitrile in the presence of sodium hydroxide gave tetrakis(1-phenyltetrazol-5-yloxymethyl)methane. Sulfur-containing analog of the latter was obtained by alkylation of 1-phenyl-4,5-dihydrotetrazole-5-thione with 1,3-dibromo-2,2-bis-(bromomethyl)propane. Nitration of the resulting polytetrazoles afforded the corresponding tetrakis(p-nitrophenyl) derivatives which can be used in the synthesis of tetrazole-containing dendrimers according to the divergent scheme.

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Authors and Affiliations

  1. St. Petersburg State Institute of Technology, Moskovskii pr. 26, 190013, St. Petersburg, Russia

    T. V. Artamonova, M. V. Zatsepina & G. I. Koldobskii

Authors
  1. T. V. Artamonova
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  2. M. V. Zatsepina
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  3. G. I. Koldobskii
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Additional information

Translated from Zhurnal Organicheskoi Khimii, Vol. 40, No. 9, 2004, pp. 1366–1368.

Original Russian Text Copyright © 2004 by Artamonova, Zatsepina, Koldobskii.

For communication XLVI, see [1].

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Artamonova, T.V., Zatsepina, M.V. & Koldobskii, G.I. Tetrazoles: XLVII. A route to tetrazole-containing dendrimers. Russ J Org Chem 40, 1318–1321 (2004). https://doi.org/10.1007/s11178-005-0013-5

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  • DOI: https://doi.org/10.1007/s11178-005-0013-5

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