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Oxidation of aromatic compounds: XII. Regio- and stereoselective oxidative dimerization of alkyl 3-arylpropynoates in the system CF3CO2H-CH2Cl2-PbO2

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Abstract

Regio- and stereoselective oxidative dimerization of alkyl 3-arylpropynoates in the system CF3CO2H-CH2Cl2-PbO2 (1–30 h, 0–20°C) leads to dialkyl (E)-2,3-bis(arylcarbonyl)-2-butene-1,4-dioates with trans arrangement of the substituents at the double bond.

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Authors and Affiliations

  1. St. Petersburg State Academy of Forestry Engineering, Institutskii per. 5, 194021, St. Petersburg, Russia

    P. Yu. Savechenkov, A. V. Vasil’ev & A. P. Rudenko

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  1. P. Yu. Savechenkov
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  2. A. V. Vasil’ev
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  3. A. P. Rudenko
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Additional information

Translated from Zhurnal Organicheskoi Khimii, Vol. 40, No. 9, 2004, pp. 1329–1333.

Original Russian Text Copyright © 2004 by Savechenkov, Vasil’ev, Rudenko.

For communication XI, see [1].

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Savechenkov, P.Y., Vasil’ev, A.V. & Rudenko, A.P. Oxidation of aromatic compounds: XII. Regio- and stereoselective oxidative dimerization of alkyl 3-arylpropynoates in the system CF3CO2H-CH2Cl2-PbO2 . Russ J Org Chem 40, 1279–1283 (2004). https://doi.org/10.1007/s11178-005-0005-5

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  • DOI: https://doi.org/10.1007/s11178-005-0005-5

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