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Molecular Polarizability of Organic Compounds and Their Complexes: XLVIII. Molar Volumes of Benzene Derivatives in Solutions at Infinite Dilution, Their Additivity, and Correlation with the Dipole Moments and Kerr Constants

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Abstract

Extrapolation formulas were derived for determination of the molar volume of a solute at infinite dilution. This quantity is stable to solvent replacement and additive with respect to increments of substituents in polysubstituted benzenes. The molar polarization and molar Kerr constant of a solute can be expressed through the molar volumes of the solute at infinite dilution and of the solvent. Replacement of the molar volume in the calculation formulas by the quantity calculated by the additive scheme considerably reduces the experimental time required for determining the dipole moments and Kerr constants of compounds in solution.

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Authors and Affiliations

  1. Rostov State University of Ways of Communication, Rostov-on-Don, Russia

    S. B. Bulgarevich, T. V. Burdastykh & L. G. Tishchenko

  2. Rostov State University, Rostov-on-Don, Russia

    I. V. Kosheleva

Authors
  1. S. B. Bulgarevich
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  2. T. V. Burdastykh
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  3. L. G. Tishchenko
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  4. I. V. Kosheleva
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__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 11, 2005, pp. 1866–1873.

Original Russian Text Copyright © 2005 by Bulgarevich, Burdastykh, Tishchenko, Kosheleva.

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Bulgarevich, S.B., Burdastykh, T.V., Tishchenko, L.G. et al. Molecular Polarizability of Organic Compounds and Their Complexes: XLVIII. Molar Volumes of Benzene Derivatives in Solutions at Infinite Dilution, Their Additivity, and Correlation with the Dipole Moments and Kerr Constants. Russ J Gen Chem 75, 1782–1789 (2005). https://doi.org/10.1007/s11176-005-0510-9

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  • DOI: https://doi.org/10.1007/s11176-005-0510-9

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